FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2883431903> ?p ?o ?g. }

• W2883431903 endingPage "134" @default.
• W2883431903 startingPage "130" @default.
• W2883431903 abstract "In this contribution, the effect of the structure of the catalytic additive – carboxylic acid – on the catalytic performance of the iron based catalyst [(PDP)Fe(OTf)2], 2 (PDP = N,N′-bis(2-pyridylmethyl)-(S,S)-2,2′-bipyrrolidine) in the selective aromatic oxidation of alkylbenzenes with H2O2 is presented. Eight (linear and branched) carboxylic acids have been tested; in the presence of 2-ethylhexanoic acid, the system [(PDP)Fe(OTf)2]/RCOOH/H2O2 has demonstrated the highest substrate conversion and the highest selectivity for oxygen incorporation into the aromatic ring (up to > 99%) at the same time. Low-temperature EPR spectroscopic study of the system [(PDP)Fe(OTf)2]/2-ethylhexanoic acid/H2O2 witness the presence of the low-spin perferryl intermediate 2aEHA with small g-factor anisotropy (g1 = 2.069, g2 = 2.007, g3 = 1.963), which directly reacts with benzene at −80 °C with the rate constant k2 = 0.6 M−1s−1, and with toluene with k2 > 1 M−1s−1, thus giving evidence for its key role in the selective oxygenation of aromatic substrates." @default.
• W2883431903 created "2018-08-03" @default.
• W2883431903 creator A5004288851 @default.
• W2883431903 creator A5035860179 @default.
• W2883431903 creator A5036615441 @default.
• W2883431903 creator A5061919209 @default.
• W2883431903 creator A5072770213 @default.
• W2883431903 date "2018-09-01" @default.
• W2883431903 modified "2023-10-18" @default.
• W2883431903 title "Effect of different carboxylic acids on the aromatic hydroxylation with H2O2 in the presence of an iron aminopyridine complex" @default.
• W2883431903 cites W1527193239 @default.
• W2883431903 cites W1888343530 @default.
• W2883431903 cites W1972555729 @default.
• W2883431903 cites W1985935792 @default.
• W2883431903 cites W1986513799 @default.
• W2883431903 cites W1991442202 @default.
• W2883431903 cites W2019406135 @default.
• W2883431903 cites W2031434538 @default.
• W2883431903 cites W2039499832 @default.
• W2883431903 cites W2050412574 @default.
• W2883431903 cites W2055247014 @default.
• W2883431903 cites W2076655264 @default.
• W2883431903 cites W2079255657 @default.
• W2883431903 cites W2084589958 @default.
• W2883431903 cites W2087003279 @default.
• W2883431903 cites W2093490569 @default.
• W2883431903 cites W2139399189 @default.
• W2883431903 cites W2142743009 @default.
• W2883431903 cites W2300849766 @default.
• W2883431903 cites W2316012065 @default.
• W2883431903 cites W2316846217 @default.
• W2883431903 cites W2469624310 @default.
• W2883431903 cites W2509986586 @default.
• W2883431903 cites W2524043541 @default.
• W2883431903 cites W2551091103 @default.
• W2883431903 cites W2762932026 @default.
• W2883431903 cites W2766319209 @default.
• W2883431903 cites W2793117617 @default.
• W2883431903 cites W2801856951 @default.
• W2883431903 cites W2807230683 @default.
• W2883431903 cites W2808773946 @default.
• W2883431903 cites W4250416537 @default.
• W2883431903 cites W4376453088 @default.
• W2883431903 doi "https://doi.org/10.1016/j.jorganchem.2018.07.016" @default.
• W2883431903 hasPublicationYear "2018" @default.
• W2883431903 type Work @default.
• W2883431903 sameAs 2883431903 @default.
• W2883431903 citedByCount "9" @default.
• W2883431903 countsByYear W28834319032019 @default.
• W2883431903 countsByYear W28834319032020 @default.
• W2883431903 countsByYear W28834319032021 @default.
• W2883431903 countsByYear W28834319032022 @default.
• W2883431903 countsByYear W28834319032023 @default.
• W2883431903 crossrefType "journal-article" @default.
• W2883431903 hasAuthorship W2883431903A5004288851 @default.
• W2883431903 hasAuthorship W2883431903A5035860179 @default.
• W2883431903 hasAuthorship W2883431903A5036615441 @default.
• W2883431903 hasAuthorship W2883431903A5061919209 @default.
• W2883431903 hasAuthorship W2883431903A5072770213 @default.
• W2883431903 hasConcept C111368507 @default.
• W2883431903 hasConcept C118792377 @default.
• W2883431903 hasConcept C127313418 @default.
• W2883431903 hasConcept C155647269 @default.
• W2883431903 hasConcept C161790260 @default.
• W2883431903 hasConcept C178790620 @default.
• W2883431903 hasConcept C181199279 @default.
• W2883431903 hasConcept C185592680 @default.
• W2883431903 hasConcept C192386470 @default.
• W2883431903 hasConcept C2776041390 @default.
• W2883431903 hasConcept C2777289219 @default.
• W2883431903 hasConcept C2777691172 @default.
• W2883431903 hasConcept C2778142098 @default.
• W2883431903 hasConcept C2779074116 @default.
• W2883431903 hasConcept C2779348937 @default.
• W2883431903 hasConcept C2781109383 @default.
• W2883431903 hasConcept C32909587 @default.
• W2883431903 hasConceptScore W2883431903C111368507 @default.
• W2883431903 hasConceptScore W2883431903C118792377 @default.
• W2883431903 hasConceptScore W2883431903C127313418 @default.
• W2883431903 hasConceptScore W2883431903C155647269 @default.
• W2883431903 hasConceptScore W2883431903C161790260 @default.
• W2883431903 hasConceptScore W2883431903C178790620 @default.
• W2883431903 hasConceptScore W2883431903C181199279 @default.
• W2883431903 hasConceptScore W2883431903C185592680 @default.
• W2883431903 hasConceptScore W2883431903C192386470 @default.
• W2883431903 hasConceptScore W2883431903C2776041390 @default.
• W2883431903 hasConceptScore W2883431903C2777289219 @default.
• W2883431903 hasConceptScore W2883431903C2777691172 @default.
• W2883431903 hasConceptScore W2883431903C2778142098 @default.
• W2883431903 hasConceptScore W2883431903C2779074116 @default.
• W2883431903 hasConceptScore W2883431903C2779348937 @default.
• W2883431903 hasConceptScore W2883431903C2781109383 @default.
• W2883431903 hasConceptScore W2883431903C32909587 @default.
• W2883431903 hasFunder F4320321079 @default.
• W2883431903 hasLocation W28834319031 @default.
• W2883431903 hasOpenAccess W2883431903 @default.
• W2883431903 hasPrimaryLocation W28834319031 @default.
• W2883431903 hasRelatedWork W1973633277 @default.

• next