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- W2883621617 abstract "Unsubstituted phthalocyanines (including free-base H2Pc and many of its metal complexes) are among the most stable organic compounds. They can sublime without decomposition under reduced pressure and temperatures of up to 550 °C. This property was previously employed to design a novel approach to noncovalent functionalization of pristine single-walled carbon nanotubes (SWNTs) with 3d metal(II) phthalocyanine complexes. However, when we attempted to use the same sublimation protocol to prepare a SWNTs-H2Pc hybrid, an unexpected side effect of partial H2Pc pyrolysis was detected, phthalonitrile being a main decomposition product, under the conditions when H2Pc is supposed to be totally stable. By using density functional theory calculations, we offer an explanation for the thermal behavior of H2Pc based on its covalent attachment to the pentagonal-ring topological defects, which are very common in all graphene-derived carbon nanomaterials and capable of reacting with amines via nucleophilic addition process." @default.
- W2883621617 created "2018-08-03" @default.
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- W2883621617 date "2018-07-19" @default.
- W2883621617 modified "2023-10-03" @default.
- W2883621617 title "Carbon Nanotubes and Graphene Promote Pyrolysis of Free-Base Phthalocyanine" @default.
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- W2883621617 doi "https://doi.org/10.1021/acs.jpclett.8b02141" @default.
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