Matches in SemOpenAlex for { <https://semopenalex.org/work/W2883647989> ?p ?o ?g. }
- W2883647989 endingPage "11450" @default.
- W2883647989 startingPage "11445" @default.
- W2883647989 abstract "The introduction of mechanophores into polymers makes it possible to transduce mechanical forces into chemical reactions that can be used to impart functions such as self-healing, catalytic activity, and mechanochromic response. Here, an example of mechanically induced metal ion release from a polymer is reported. Ferrocene (Fc) was incorporated as an iron ion releasing mechanophore into poly(methyl acrylate)s (PMAs) and polyurethanes (PUs). Sonication triggered the preferential cleavage of the polymers at the Fc units over other bonds, as shown by a kinetic study of the molar mass distribution of the cleaved Fc-containing and Fc-free reference polymers. The released and oxidized iron ions can be detected with KSCN to generate the red-colored [Fe(SCN)n (H2 O)6-n )](3-n)+ complex or reacted with K4 [Fe(CN)6 ] to afford Prussian blue." @default.
- W2883647989 created "2018-08-03" @default.
- W2883647989 creator A5022881573 @default.
- W2883647989 creator A5040427898 @default.
- W2883647989 creator A5061638501 @default.
- W2883647989 creator A5062444374 @default.
- W2883647989 creator A5075032685 @default.
- W2883647989 creator A5079984092 @default.
- W2883647989 date "2018-07-26" @default.
- W2883647989 modified "2023-10-12" @default.
- W2883647989 title "Triggered Metal Ion Release and Oxidation: Ferrocene as a Mechanophore in Polymers" @default.
- W2883647989 cites W105014408 @default.
- W2883647989 cites W1966744510 @default.
- W2883647989 cites W1967828255 @default.
- W2883647989 cites W1970863842 @default.
- W2883647989 cites W1974996078 @default.
- W2883647989 cites W1975225288 @default.
- W2883647989 cites W1976915943 @default.
- W2883647989 cites W1978088151 @default.
- W2883647989 cites W1979804238 @default.
- W2883647989 cites W1983318144 @default.
- W2883647989 cites W1983531928 @default.
- W2883647989 cites W1984830738 @default.
- W2883647989 cites W1999330727 @default.
- W2883647989 cites W2008606095 @default.
- W2883647989 cites W2009842982 @default.
- W2883647989 cites W2010165618 @default.
- W2883647989 cites W2010617308 @default.
- W2883647989 cites W2012850876 @default.
- W2883647989 cites W2013300088 @default.
- W2883647989 cites W2013967630 @default.
- W2883647989 cites W2015971856 @default.
- W2883647989 cites W2016676022 @default.
- W2883647989 cites W2019531889 @default.
- W2883647989 cites W2022076374 @default.
- W2883647989 cites W2036037731 @default.
- W2883647989 cites W2038829642 @default.
- W2883647989 cites W2043008468 @default.
- W2883647989 cites W2043254339 @default.
- W2883647989 cites W2043639361 @default.
- W2883647989 cites W2046886357 @default.
- W2883647989 cites W2047755968 @default.
- W2883647989 cites W2050588701 @default.
- W2883647989 cites W2051769448 @default.
- W2883647989 cites W2055836301 @default.
- W2883647989 cites W2070579483 @default.
- W2883647989 cites W2073089708 @default.
- W2883647989 cites W2080488246 @default.
- W2883647989 cites W2093062749 @default.
- W2883647989 cites W2095111591 @default.
- W2883647989 cites W2098872834 @default.
- W2883647989 cites W2118497276 @default.
- W2883647989 cites W2126501716 @default.
- W2883647989 cites W2129201801 @default.
- W2883647989 cites W2133062319 @default.
- W2883647989 cites W2136273784 @default.
- W2883647989 cites W2139187462 @default.
- W2883647989 cites W2141947008 @default.
- W2883647989 cites W2144081123 @default.
- W2883647989 cites W2161792378 @default.
- W2883647989 cites W2161915253 @default.
- W2883647989 cites W2166624342 @default.
- W2883647989 cites W2195295975 @default.
- W2883647989 cites W2206179108 @default.
- W2883647989 cites W2276307662 @default.
- W2883647989 cites W2283962600 @default.
- W2883647989 cites W2287970811 @default.
- W2883647989 cites W2313446698 @default.
- W2883647989 cites W2313961448 @default.
- W2883647989 cites W2315161406 @default.
- W2883647989 cites W2317870047 @default.
- W2883647989 cites W2323365494 @default.
- W2883647989 cites W2327370759 @default.
- W2883647989 cites W2332519603 @default.
- W2883647989 cites W2404159137 @default.
- W2883647989 cites W2415904663 @default.
- W2883647989 cites W4232932958 @default.
- W2883647989 cites W4234292567 @default.
- W2883647989 cites W4236358358 @default.
- W2883647989 cites W4248963492 @default.
- W2883647989 cites W613095668 @default.
- W2883647989 doi "https://doi.org/10.1002/anie.201803524" @default.
- W2883647989 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29897637" @default.
- W2883647989 hasPublicationYear "2018" @default.
- W2883647989 type Work @default.
- W2883647989 sameAs 2883647989 @default.
- W2883647989 citedByCount "95" @default.
- W2883647989 countsByYear W28836479892018 @default.
- W2883647989 countsByYear W28836479892019 @default.
- W2883647989 countsByYear W28836479892020 @default.
- W2883647989 countsByYear W28836479892021 @default.
- W2883647989 countsByYear W28836479892022 @default.
- W2883647989 countsByYear W28836479892023 @default.
- W2883647989 crossrefType "journal-article" @default.
- W2883647989 hasAuthorship W2883647989A5022881573 @default.
- W2883647989 hasAuthorship W2883647989A5040427898 @default.
- W2883647989 hasAuthorship W2883647989A5061638501 @default.
- W2883647989 hasAuthorship W2883647989A5062444374 @default.