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- W2883672907 abstract "An efficient Fe(TPP)Cl catalyzed insertion reaction of in situ generated benzylic carbenes from N-tosylhydrazones into X-H (X = Si, Sn, Ge) was developed. Silanes bearing tertiary, secondary, and primary (3°, 2°, and 1°) Si-H bonds all reacted well to afford insertion products in moderate to high yields (up to 97%), and the reaction time could be significantly shortened to 1 h under microwave irradiation. A programmable stepwise double insertion strategy was developed for the synthesis of unsymmetrical tetrasubstituted silanes." @default.
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- W2883672907 date "2018-07-25" @default.
- W2883672907 modified "2023-10-16" @default.
- W2883672907 title "Iron Porphyrin Catalyzed Insertion Reaction of <i>N</i>-Tosylhydrazone-Derived Carbenes into X–H (X = Si, Sn, Ge) Bonds" @default.
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- W2883672907 doi "https://doi.org/10.1021/acs.orglett.8b01931" @default.
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