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• W2883691626 abstract "Abstract The involvements of in vivo reactive oxygen species, such as superoxide radical (O 2 .− ), peroxynitrite (ONOO − ), hydrogen peroxide (H 2 O 2 ), hydroxyl radical ( . OH), peroxyl radical ( . OOH), nitrogen oxide radical (NO . ), etc in cancer and other diseases are well documented. However, the availability of biosensing elements to detect the presence of reactive oxygen species inside living cells is rare. Herein, B3LYP−D3 dispersion‐corrected density functional theory has been used to design different porous frameworks by coordinating several divalent transition metals, such as Mn +2 , Fe +2 , Co +2 , Cu +2 , and Zn +2 with cysteine (Cys) that can detect the presence of various reactive oxygen species. It is found that among all the metals, Cu +2 has the strongest interaction with Cys, thereby producing several stable porous frameworks. Among these frameworks, [Cys‐Cu +2 ] 3 ( 8‐1 ) is found to possess the largest pore and can adsorb both the anionic (O 2 .− , ONOO .− ) and neutral reactive oxygen species ( . OH, . OOH, and NO . ) in the aqueous environment. It is thus proposed that the elongation of [Cys‐Cu +2 ] 3 ( 8‐1 ) framework can generate a novel biosensing element, which can be used for the sensing of various reactive oxygen species. However, experimental verification of the proposed material is required to confirm its applicability." @default.
• W2883691626 created "2018-08-03" @default.
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• W2883691626 date "2018-07-17" @default.
• W2883691626 modified "2023-09-27" @default.
• W2883691626 title "Cysteine‐metal Porous Frameworks as Biosensing Elements for the Adsorption of Reactive Oxygen Species" @default.
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• W2883691626 doi "https://doi.org/10.1002/slct.201800537" @default.
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