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- W2883777749 abstract "Structural characterization of the compound [Cu(C 2 H 3 N)(C 23 H 23 N 3 O)](ClO 4 ) 2 ] or [Cu(C 2 H 3 N)(DQMEA)](ClO 4 ) 2 ] [DQMEA = 2-methoxy- N , N -bis(quinolin-2-ylmethyl)ethylamine] {systematic name: (acetonitrile)[2-methoxy- N , N -bis(quinolin-2-ylmethyl)ethylamine]copper(II) diperchlorate} by single-crystal X-ray diffraction reveals a complex cation with a tetradentate coordination of the DQMEA ligand along with monodentate coordination of a CH 3 CN ligand to a single Cu II center, with two perchlorate anions providing charge balance. The Cu II center has a distorted square-pyramidal geometry in which the nitrogen atoms of the DQMEA and CH 3 CN ligands occupy the equatorial positions, while the oxygen atom of the DQMEA ligand resides in the axial position with an elongated Cu—O bond. The quinoline ring systems are nearly co-planar in the structure, while the linear CH 3 CN ligand is tilted significantly below this plane, and the central nitrogen of DQMEA is above it. Within the complex, weak C—H...N hydrogen bonding takes place between the nitrogen of CH 3 CN and a neighboring quinolyl group. The perchlorate ions are disordered within the structure, but undergo a number of weak intermolecular C—H...O hydrogen-bonding interactions. Additional weak π-stacking interactions between the quinolyl groups of neighboring complexes further stabilize the crystal packing." @default.
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- W2883777749 date "2018-07-24" @default.
- W2883777749 modified "2023-09-23" @default.
- W2883777749 title "Crystal structure of a mononuclear copper(II) complex with 2-methoxy-N,N-bis(quinolin-2-ylmethyl)ethylamine (DQMEA)" @default.
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- W2883777749 doi "https://doi.org/10.1107/s2056989018010319" @default.
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