FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2883804512> ?p ?o ?g. }

• W2883804512 abstract "Aggregated cyanines form ordered supramolecular structures with the potential to transport energy efficiently over long distances, a hallmark of photosynthetic light-harvesting complexes. In concentrated aqueous solution, pseudoisocyanine (PIC) spontaneously forms fibers with a chiral J-band red-shifted 1600 cm−1 from the monomeric 0–0 transition. A cryogenic transmission electron microscopy analysis of these fibers show an average fiber width of 2.89 nm, although the molecular-level structure of the aggregate is currently unknown. To determine a molecular model for these PIC fibers, the calculated spectra and dynamics using a Frenkel exciton model are compared to experiment. A chiral aggregate model in which the PIC monomers are neither parallel nor orthogonal to the long axis of the fiber is shown to replicate the experimental spectra most closely. This model can be physically realized by the sequential binding of PIC dimers and monomers to the ends of the fiber. These insights into the molecular aggregation model for aqueous PIC can also be applied to other similar cyanine-based supramolecular complexes with the potential for long-range energy transport, a key building block for the rational design of novel excitonic systems." @default.
• W2883804512 created "2018-08-03" @default.
• W2883804512 creator A5024170542 @default.
• W2883804512 creator A5029903707 @default.
• W2883804512 creator A5075152359 @default.
• W2883804512 creator A5087749560 @default.
• W2883804512 date "2018-07-13" @default.
• W2883804512 modified "2023-09-24" @default.
• W2883804512 title "Molecular model of J-aggregated pseudoisocyanine fibers" @default.
• W2883804512 cites W1506906952 @default.
• W2883804512 cites W1965092590 @default.
• W2883804512 cites W1969510290 @default.
• W2883804512 cites W1990566970 @default.
• W2883804512 cites W1997647405 @default.
• W2883804512 cites W1999888201 @default.
• W2883804512 cites W2006973993 @default.
• W2883804512 cites W2009237413 @default.
• W2883804512 cites W2012784671 @default.
• W2883804512 cites W2033808028 @default.
• W2883804512 cites W2035579953 @default.
• W2883804512 cites W2036734876 @default.
• W2883804512 cites W2043879343 @default.
• W2883804512 cites W2045656514 @default.
• W2883804512 cites W2046412723 @default.
• W2883804512 cites W2046424037 @default.
• W2883804512 cites W2046428633 @default.
• W2883804512 cites W2046545247 @default.
• W2883804512 cites W2049221592 @default.
• W2883804512 cites W2050929241 @default.
• W2883804512 cites W2055563809 @default.
• W2883804512 cites W2058363175 @default.
• W2883804512 cites W2058398316 @default.
• W2883804512 cites W2063785360 @default.
• W2883804512 cites W2067378215 @default.
• W2883804512 cites W2069688935 @default.
• W2883804512 cites W2079625967 @default.
• W2883804512 cites W2087293954 @default.
• W2883804512 cites W2088344782 @default.
• W2883804512 cites W2092157292 @default.
• W2883804512 cites W2097552134 @default.
• W2883804512 cites W2100337713 @default.
• W2883804512 cites W2112309199 @default.
• W2883804512 cites W2113499713 @default.
• W2883804512 cites W2117474780 @default.
• W2883804512 cites W2123681603 @default.
• W2883804512 cites W2128308727 @default.
• W2883804512 cites W2143981217 @default.
• W2883804512 cites W2151781484 @default.
• W2883804512 cites W2160070976 @default.
• W2883804512 cites W2230728100 @default.
• W2883804512 cites W2315878609 @default.
• W2883804512 cites W2326053813 @default.
• W2883804512 cites W2527394345 @default.
• W2883804512 cites W2565032834 @default.
• W2883804512 cites W2596869311 @default.
• W2883804512 cites W2604003743 @default.
• W2883804512 cites W2612746433 @default.
• W2883804512 cites W2623232976 @default.
• W2883804512 cites W2770566781 @default.
• W2883804512 cites W2770774715 @default.
• W2883804512 cites W2785471146 @default.
• W2883804512 cites W2790384938 @default.
• W2883804512 doi "https://doi.org/10.1063/1.5036656" @default.
• W2883804512 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6045493" @default.
• W2883804512 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30007374" @default.
• W2883804512 hasPublicationYear "2018" @default.
• W2883804512 type Work @default.
• W2883804512 sameAs 2883804512 @default.
• W2883804512 citedByCount "10" @default.
• W2883804512 countsByYear W28838045122019 @default.
• W2883804512 countsByYear W28838045122020 @default.
• W2883804512 countsByYear W28838045122021 @default.
• W2883804512 countsByYear W28838045122022 @default.
• W2883804512 countsByYear W28838045122023 @default.
• W2883804512 crossrefType "journal-article" @default.
• W2883804512 hasAuthorship W2883804512A5024170542 @default.
• W2883804512 hasAuthorship W2883804512A5029903707 @default.
• W2883804512 hasAuthorship W2883804512A5075152359 @default.
• W2883804512 hasAuthorship W2883804512A5087749560 @default.
• W2883804512 hasBestOaLocation W28838045123 @default.
• W2883804512 hasConcept C115624301 @default.
• W2883804512 hasConcept C120665830 @default.
• W2883804512 hasConcept C121332964 @default.
• W2883804512 hasConcept C1276947 @default.
• W2883804512 hasConcept C147789679 @default.
• W2883804512 hasConcept C159467904 @default.
• W2883804512 hasConcept C166940927 @default.
• W2883804512 hasConcept C17729963 @default.
• W2883804512 hasConcept C178790620 @default.
• W2883804512 hasConcept C184651966 @default.
• W2883804512 hasConcept C185592680 @default.
• W2883804512 hasConcept C192562407 @default.
• W2883804512 hasConcept C26873012 @default.
• W2883804512 hasConcept C2777324032 @default.
• W2883804512 hasConcept C2778060476 @default.
• W2883804512 hasConcept C4839761 @default.
• W2883804512 hasConcept C519885992 @default.
• W2883804512 hasConcept C521977710 @default.
• W2883804512 hasConcept C8010536 @default.
• W2883804512 hasConcept C91881484 @default.

• next