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- W2884102129 abstract "Grafting polyolefin chains onto the surface of silica nanoparticles to form satisfactory polyolefin/silica nanocomposites still remains a challenge, even after the complicated functionalization of the polyolefin chains and surface modification of the silica. In this study, an efficient route for the preparation of polypropylene-grafted nanosilica (PP-g-SiO2) masterbatch was presented through the reactive melt blending of maleic-anhydride-grafted polypropylene (PP-MAH) and amino-functionalized silica (SN-NH2) synthesized by the co-condensation method. The amount of grafted PP chains could achieve to 80.8 wt%. And PP-g-SiO2 exhibited fine dispersion in PP matrix. The shear and extension rheology results of PP/PP-g-SiO2 nanocomposites showed that melt strength of PP could be enhanced remarkably by incorporation of PP-g-SiO2 masterbatch, which revealed the strong interactions between PP-g-SiO2 and PP matrix. These findings provide a facile way to prepare polyolefin-grafted nanosilica, while expanding the potential applications of nanosilica in polyolefin nanocomposites." @default.
- W2884102129 created "2018-08-03" @default.
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- W2884102129 date "2018-08-01" @default.
- W2884102129 modified "2023-10-18" @default.
- W2884102129 title "Efficient grafting of polypropylene onto silica nanoparticles and the properties of PP/PP-g-SiO2 nanocomposites" @default.
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- W2884102129 doi "https://doi.org/10.1016/j.polymer.2018.07.060" @default.
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