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- W2884165645 abstract "Conductive polymers are of great importance in a variety of chemistry-related disciplines and applications. The recently developed bottom-up on-surface synthesis strategy provides us with opportunities for the fabrication of various nanostructures in a flexible and facile manner, which could be investigated by high-resolution microscopic techniques in real space. Herein, we designed and synthesized molecular precursors functionalized with benzal gem-dibromomethyl groups. A combination of scanning tunneling microscopy, noncontact atomic force microscopy, high-resolution synchrotron radiation photoemission spectroscopy, and density functional theory calculations demonstrated that it is feasible to achieve the direct formation of C–C double-bonded structural motifs via on-surface dehalogenative homocoupling reactions on the Au(111) surface. Correspondingly, we convert the sp3-hybridized state to an sp2-hybridized state of carbon atoms, i.e., from an alkyl group to an alkenyl one. Moreover, by such a bottom-up strategy, we have successfully fabricated poly(phenylenevinylene) chains on the surface, which is anticipated to inspire further studies toward understanding the nature of conductive polymers at the atomic scale." @default.
- W2884165645 created "2018-08-03" @default.
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- W2884165645 date "2018-07-17" @default.
- W2884165645 modified "2023-10-17" @default.
- W2884165645 title "Direct Formation of C–C Double-Bonded Structural Motifs by On-Surface Dehalogenative Homocoupling of <i>gem</i>-Dibromomethyl Molecules" @default.
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- W2884165645 doi "https://doi.org/10.1021/acsnano.8b02459" @default.
- W2884165645 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30016072" @default.