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• W2884199423 endingPage "463" @default.
• W2884199423 startingPage "450" @default.
• W2884199423 abstract "Volcanogenic halogens, in particular bromine, potentially play an important role in the ozone depletion of the atmosphere. Understanding bromine behaviour in magmas is therefore crucial to properly evaluate the contribution of volcanic eruptions to atmospheric chemistry and their environmental impact. To date, bromine partitioning between silicate melts and the gas phase is very poorly constrained, with the only relevant experimental studies limited to investigation of synthetic melt with silicic compositions. In this study, fluid/melt partitioning experiments were performed using natural silicate glasses with mafic, intermediate and silicic compositions. For each composition, experiments were run with various Br contents in the initial fluid (H2O–NaBr), at T–P conditions representative of shallow magmatic reservoirs in volcanic arc contexts (100–200 MPa, 900–1200 °C). The resulting fluid/melt partition coefficients (DBrf/m) are: 5.0 ± 0.3 at 1200 °C–100 MPa for the basalt, 9.1 ± 0.6 at 1060 °C–200 MPa for the andesite and 20.2 ± 1.2 at 900 °C–200 MPa for the rhyodacite. Our experiments show that DBrf/m increases with increasing SiO2 content of the melt (as for chlorine) and suggest that it is also sensitive to melt temperature (increase of DBrf/m with decreasing temperature). We develop a simple model to predict the S–Cl–Br degassing behaviour in mafic systems, which accounts for the variability of S–Cl–Br compositions of volcanic gases from Etna and other mafic systems, and shows that coexisting magmatic gas and melt evolve from S-rich to Cl–Br enriched (relative to S) upon increasing degree of degassing. We also report first Br contents for melt inclusions from Etna, Stromboli, Merapi and Santorini eruptions and calculate the mass of bromine available in the magma reservoir prior to the eruptions under consideration. The discrepancy that we highlight between the mass of Br in the co-existing melt and fluid prior to the Merapi 2010 eruption (433 and 73 tons, respectively) and the lack of observed BrO (from space) hints at the need to investigate further Br speciation in ‘ash-rich’ volcanic plumes. Overall, our results suggest that the Br yield into the atmosphere of cold and silicic magmas will be much larger than that from hotter and more mafic magmas." @default.
• W2884199423 created "2018-08-03" @default.
• W2884199423 creator A5012200240 @default.
• W2884199423 creator A5020187720 @default.
• W2884199423 creator A5027998868 @default.
• W2884199423 creator A5031862821 @default.
• W2884199423 creator A5045529630 @default.
• W2884199423 creator A5047374378 @default.
• W2884199423 creator A5061966291 @default.
• W2884199423 creator A5068516775 @default.
• W2884199423 creator A5081354153 @default.
• W2884199423 date "2018-09-01" @default.
• W2884199423 modified "2023-10-13" @default.
• W2884199423 title "The role of melt composition on aqueous fluid vs. silicate melt partitioning of bromine in magmas" @default.
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