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• W2884215253 abstract "Coordination polymers (CPs) consisting of alkali metals (Na, K, Rb, and Cs) and a powerful nitrogen- and oxygen-rich energetic ligand (4,4'-bis(dinitromethyl)-3,3'-bisnitramide-methylene-furazanate, DBMF2- ) were developed. Molecular structures of these CPs, confirmed by single-crystal X-ray diffraction analysis, indicated that the same ligand takes on a U-shaped state for Na and an N-shaped state for K, Rb, and Cs. Explosion tests demonstrated that both Na2 DBMF and K2 DBMF efficiently detonated the secondary explosive RDX. This indicates that they are both effective primary explosives. K2 DBMF exhibits better calculated detonation performance (D: 8227 m s-1 ; P: 32.5 GPa) than the primary explosive Pb(N3 )2 . In addition, toxicity tests and evaluation of their decomposition products reveal their low impact on the environment. Both experimental results and theoretical analyses indicate that the combination of alkali metals and a powerful energetic ligand can stimulate the development of primary explosives." @default.
• W2884215253 created "2018-08-03" @default.
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• W2884215253 date "2018-08-27" @default.
• W2884215253 modified "2023-10-18" @default.
• W2884215253 title "Alkali Metals‐Based Energetic Coordination Polymers as Promising Primary Explosives: Crystal Structures, Energetic Properties, and Environmental Impact" @default.
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• W2884215253 doi "https://doi.org/10.1002/chem.201802494" @default.
• W2884215253 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30014531" @default.
• W2884215253 hasPublicationYear "2018" @default.
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