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• W2884268269 abstract "Thin Film Technology has attracted attention of the numerous investigators all over the world owing to its huge applications in a variety of fields such as optics, electronics, lasers, blue-green light emitting diodes and industries also. There are a variety of deposition techniques by which a host of thin semiconductor films can be deposited. Among these deposition technologies, chemical bath deposition (CBD) is ranked as conceptually simplest and universal. In this paper, we report on the synthesis of Zn1-xCoxSe (0≤x≤0.275) thin films grown from the aqueous solutions of zinc sulphate, cobaltous sulphate and selenium metal ions in the presence of TEA as a complexing agent, hydrazine hydrate as a reducing agent and ammonia to enhance the film adherence. ZnSe and Co doped ZnSe films were prepared at 80°± 1° C; the deposition time being 90 mins. The surface of the as- obtained films were smooth, uniform and hydrophobic in nature. The X-ray photoelectron spectroscopy confirmed the presence of Zn, Co and Se. As the constituent elements in the deposited films are having 2+, 2+ and 2- chemical states. Both ZnSe and Zn1-xCoxSe thin films are crystalline over the whole composition range (0≤x≤0.275) and are structurally cubic. The lattice parameter (a) and interplanar distance (d) change with the addition of Co2+ in the ZnSe host lattice. Formation of ternary alloy was confirmed from the shift in the (111) X-ray diffraction peak. AFM surface topography revealed the influence of Co2+ integration into ZnSe host lattice, the film sample with x=0.15 being more crystalline with Sku=5.572, maximum surface area ratio (Sdr) and highest average roughness (Sa). Increasing amount of Co2+ in the ZnSe lattice results in the sample surface transformation from mesokurtic (less sharp or crystalline) to leptokurtic (crystalline or more sharper). The advanced imaging Sobel transformation and angular spectrum techniques provided a better visibility of the fine structure and features of the various materials." @default.
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• W2884268269 date "2018-01-01" @default.
• W2884268269 modified "2023-09-23" @default.
• W2884268269 title "Solution grown ZnSe:Co nanocrystalline thin films: The characteristic properties" @default.
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• W2884268269 doi "https://doi.org/10.1063/1.5047712" @default.
• W2884268269 hasPublicationYear "2018" @default.
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