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• W2884513194 abstract "Abstract Through self-assembly of the typical β-diketone ligand HBTFA (HBTFA = 4,4,4-trifluoro-1-phenyl-1,3-butanedione) with LnCl3·6H2O in the presence of Et3N, the six-tenth in the η2-Mode I and the four-tenth in the μ-(O)-η2-bridging Mode II of the ten BTFA− ligands, together with the involvement of two μ3-(OH)− anions, two μ1-coordinating H2O and two μ2-bridging H2O molecules, endow the formation of homoleptic cyclic tetranuclear complexes [Ln4(BTFA)10(μ3-OH)2(H2O)4] (Ln = La, 1; Eu, 2; Tb, 3 or Gd, 4), respectively. Moreover, attributing to effective ligand-to-Ln3+ transfer energy, color-purity red-light (ΦLEu = 20.1%) for complex 2 while few near-white-light (Φem = 6.4%) for complex 3 are exhibited, respectively, despite the (μ3-OH)−-and-H2O-induced OH-oscillators surrounded from the four Ln3+ ions." @default.
• W2884513194 created "2018-08-03" @default.
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• W2884513194 date "2018-09-01" @default.
• W2884513194 modified "2023-10-15" @default.
• W2884513194 title "Luminescence homoleptic cyclic tetranuclear [Ln 4 (BTFA) 10 ( μ 3 -OH) 2 (H 2 O) 4 ] complexes (Ln = Eu or Tb)" @default.
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• W2884513194 doi "https://doi.org/10.1016/j.inoche.2018.07.026" @default.
• W2884513194 hasPublicationYear "2018" @default.
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