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- W2884654671 abstract "transition is a first order magneto-structural transition, which means the magnetic transition and crystalline structure transition occur simultaneously, and completely reversible. Temperature hysteresis and phase coexistence have been found to confirm that it is a first order transformation. While for Gd5(Si0.15Ge3.85), it is partially reversible at some temperature range between the antiferromagnetic and the ferromagnetic state. For Gd5(Si2.3Ge1.7) and Gd5(Si3Ge1), it was a second order transformation between the paramagnetic and ferromagnetic state, because no ΔT have been found. Giant magnetostriction was only found on Gd5(Si1.95Ge2.05), Gd5(Si2Ge2), Gd5(Si2.09Ge1.91) in their vicinity of first order transformation. MFM images have also been taken on polycrystal sample Gd5(Si2.09Ge1.91) to investigate the transformation process. The results also indicates that the Curie temperature was lower and the thermally-induced strain higher in the sample made from lower purity level Gd starting materials compared with the sample made from high purity Gd metal. TE, MS, MFM and VSM measurements on single crystal Gd5(Si2Ge2) and Gd5(Si2.3Ge1.7) samples have shown their strong anisotropic behaviors." @default.
- W2884654671 created "2018-08-03" @default.
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- W2884654671 date "1970-01-01" @default.
- W2884654671 modified "2023-10-18" @default.
- W2884654671 title "The crystal structures of compounds involving metal-metal bonding. I. Gd<sub>8</sub>Cl<sub>12</sub>. II Te<sub>4</sub>(AlCl<sub>4</sub>)" @default.
- W2884654671 doi "https://doi.org/10.2172/4134391" @default.
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