FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2884773229> ?p ?o ?g. }

• W2884773229 abstract "A single enantiomer of a cationic phosphine, [α-CgPAmHMe]BF4, containing two asymmetric subunits, an amidinium group (AmH) and a phosphacycle (CgP), has been synthesized and isolated. The ligand, which is of an extremely rare class, has been coordinated to Rh(I), Au(I), Ag(I), Cu(I), and Pt(0) to enable an empirical assessment of its donor properties. Analysis of the IR stretching frequency of the carbonyl ligand in trans-[Rh(α-CgPAmHMe)2(CO)Cl](BF4)2 coupled with metric data obtained from crystal-state molecular structures of pertinent complexes confirms the strong π-accepting properties of the ligand. The integrity of the N-P bond is compromised upon addition of base to both [Cu(α-CgPAmHMe)Cl]BF4 and [Ag(α-CgPAmHMe)(OTf)]BF4 where, instead of isolating anticipated chelating and/or bridging forms of the neutral, deprotonated α-CgPAmMe derivative, decomposition products were obtained containing a phosphacycle fragment and/or amidine ligands. The fragility of the N-P bond is also evident in uncoordinated [α-CgPAmHMe]BF4 as treatment with aqueous base releases a neutral amidine fragment and generates the P-P dimer [α,α-CgPP(O)Cg]. These fortuitous observations show [α-CgPAmHMe]BF4 to be a very useful synthon for the potential production of novel asymmetric phosphines." @default.
• W2884773229 created "2018-08-03" @default.
• W2884773229 creator A5024889701 @default.
• W2884773229 creator A5084888196 @default.
• W2884773229 date "2018-07-20" @default.
• W2884773229 modified "2023-10-14" @default.
• W2884773229 title "Asymmetric Cationic Phosphines: Synthesis, Coordination Chemistry, and Reactivity" @default.
• W2884773229 cites W1793034939 @default.
• W2884773229 cites W1976717939 @default.
• W2884773229 cites W1980057443 @default.
• W2884773229 cites W1984021287 @default.
• W2884773229 cites W1984844030 @default.
• W2884773229 cites W1992347442 @default.
• W2884773229 cites W2007109340 @default.
• W2884773229 cites W2020112486 @default.
• W2884773229 cites W2025588793 @default.
• W2884773229 cites W2026298686 @default.
• W2884773229 cites W2030841140 @default.
• W2884773229 cites W2035340810 @default.
• W2884773229 cites W2035571885 @default.
• W2884773229 cites W2039515729 @default.
• W2884773229 cites W2040711221 @default.
• W2884773229 cites W2046568819 @default.
• W2884773229 cites W2050229878 @default.
• W2884773229 cites W2050953612 @default.
• W2884773229 cites W2054661629 @default.
• W2884773229 cites W2063032427 @default.
• W2884773229 cites W2067380495 @default.
• W2884773229 cites W2067823728 @default.
• W2884773229 cites W2068522270 @default.
• W2884773229 cites W2071918630 @default.
• W2884773229 cites W2073007954 @default.
• W2884773229 cites W2086699772 @default.
• W2884773229 cites W2091393818 @default.
• W2884773229 cites W2112848669 @default.
• W2884773229 cites W2131350133 @default.
• W2884773229 cites W2149421007 @default.
• W2884773229 cites W2275113364 @default.
• W2884773229 cites W2313144215 @default.
• W2884773229 cites W2322918983 @default.
• W2884773229 cites W2332745544 @default.
• W2884773229 cites W2341891598 @default.
• W2884773229 cites W2461580549 @default.
• W2884773229 cites W2465752534 @default.
• W2884773229 cites W2467400748 @default.
• W2884773229 cites W2486304082 @default.
• W2884773229 cites W2512740714 @default.
• W2884773229 cites W2520036133 @default.
• W2884773229 cites W2560694951 @default.
• W2884773229 cites W2582149366 @default.
• W2884773229 cites W2591867326 @default.
• W2884773229 cites W2602378487 @default.
• W2884773229 cites W2621421982 @default.
• W2884773229 cites W2764249101 @default.
• W2884773229 cites W4211240100 @default.
• W2884773229 doi "https://doi.org/10.1021/acs.inorgchem.8b01657" @default.
• W2884773229 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30028596" @default.
• W2884773229 hasPublicationYear "2018" @default.
• W2884773229 type Work @default.
• W2884773229 sameAs 2884773229 @default.
• W2884773229 citedByCount "7" @default.
• W2884773229 countsByYear W28847732292019 @default.
• W2884773229 countsByYear W28847732292020 @default.
• W2884773229 countsByYear W28847732292021 @default.
• W2884773229 countsByYear W28847732292022 @default.
• W2884773229 countsByYear W28847732292023 @default.
• W2884773229 crossrefType "journal-article" @default.
• W2884773229 hasAuthorship W2884773229A5024889701 @default.
• W2884773229 hasAuthorship W2884773229A5084888196 @default.
• W2884773229 hasBestOaLocation W28847732292 @default.
• W2884773229 hasConcept C115624301 @default.
• W2884773229 hasConcept C116569031 @default.
• W2884773229 hasConcept C118629725 @default.
• W2884773229 hasConcept C142724271 @default.
• W2884773229 hasConcept C145148216 @default.
• W2884773229 hasConcept C155647269 @default.
• W2884773229 hasConcept C161790260 @default.
• W2884773229 hasConcept C170493617 @default.
• W2884773229 hasConcept C178516000 @default.
• W2884773229 hasConcept C178790620 @default.
• W2884773229 hasConcept C183882617 @default.
• W2884773229 hasConcept C185592680 @default.
• W2884773229 hasConcept C188027245 @default.
• W2884773229 hasConcept C204787440 @default.
• W2884773229 hasConcept C2776910235 @default.
• W2884773229 hasConcept C2777716191 @default.
• W2884773229 hasConcept C2778622868 @default.
• W2884773229 hasConcept C2779546866 @default.
• W2884773229 hasConcept C40869318 @default.
• W2884773229 hasConcept C55493867 @default.
• W2884773229 hasConcept C71240020 @default.
• W2884773229 hasConcept C71924100 @default.
• W2884773229 hasConcept C8010536 @default.
• W2884773229 hasConceptScore W2884773229C115624301 @default.
• W2884773229 hasConceptScore W2884773229C116569031 @default.
• W2884773229 hasConceptScore W2884773229C118629725 @default.
• W2884773229 hasConceptScore W2884773229C142724271 @default.
• W2884773229 hasConceptScore W2884773229C145148216 @default.
• W2884773229 hasConceptScore W2884773229C155647269 @default.
• W2884773229 hasConceptScore W2884773229C161790260 @default.

• next