FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2884893670> ?p ?o ?g. }

• W2884893670 endingPage "9250" @default.
• W2884893670 startingPage "9241" @default.
• W2884893670 abstract "A detailed investigation of the overall crystal structure, and in particular of the local structure around the cations in M2La3Sb3O14 (M = Mg, Ca) was accomplished using X-ray diffraction, steady state luminescence spectroscopy and decay kinetics, and state of the art density functional calculations. The computational tool was also used to investigate the structure of Mn2La3Sb3O14. The Eu3+ dopant ion was employed as an optical probe of the local symmetry at the cationic sites. The use of these complementary techniques shows that the antimonates under investigation belong to the rhombohedral pyrochlore family with space group R3̅m (No. 166), but while Mg2La3Sb3O14 and Mn2La3Sb3O14 show an ordered cationic configuration, the Ca2+ and La3+ of Ca2La3Sb3O14 are disordered because of their similar ionic radii. In both the Mg- and the Ca-based compounds, the Eu3+ ions formally occupy centrosymmetric sites, but in the case of Ca2La3Sb3O14 the presence of disorder in the outer coordination spheres removes the local inversion symmetry in these sites. This has a strong influence on the Eu3+ luminescence spectrum and on the radiative decay rate of the 5D0 emitting level." @default.
• W2884893670 created "2018-08-03" @default.
• W2884893670 creator A5026155734 @default.
• W2884893670 creator A5026209005 @default.
• W2884893670 creator A5051847614 @default.
• W2884893670 creator A5058456003 @default.
• W2884893670 creator A5069807123 @default.
• W2884893670 date "2018-07-17" @default.
• W2884893670 modified "2023-09-25" @default.
• W2884893670 title "Disorder-Induced Breaking of the Local Inversion Symmetry in Rhombohedral Pyrochlores M₂La₃Sb₃O₁₄ (M = Mg or Ca): A Structural and Spectroscopic Investigation" @default.
• W2884893670 cites W1480213437 @default.
• W2884893670 cites W1644309230 @default.
• W2884893670 cites W1966229911 @default.
• W2884893670 cites W1974669271 @default.
• W2884893670 cites W1987455219 @default.
• W2884893670 cites W1989179549 @default.
• W2884893670 cites W1995892089 @default.
• W2884893670 cites W1999374672 @default.
• W2884893670 cites W2021050313 @default.
• W2884893670 cites W2023209083 @default.
• W2884893670 cites W2027666703 @default.
• W2884893670 cites W2032698343 @default.
• W2884893670 cites W2032743846 @default.
• W2884893670 cites W2036113194 @default.
• W2884893670 cites W2044962378 @default.
• W2884893670 cites W2051245001 @default.
• W2884893670 cites W2068274298 @default.
• W2884893670 cites W2078149562 @default.
• W2884893670 cites W2083919129 @default.
• W2884893670 cites W2084815941 @default.
• W2884893670 cites W2127069478 @default.
• W2884893670 cites W2167590372 @default.
• W2884893670 cites W2169449785 @default.
• W2884893670 cites W2202109057 @default.
• W2884893670 cites W2324478698 @default.
• W2884893670 cites W2326411711 @default.
• W2884893670 cites W2518782562 @default.
• W2884893670 cites W2950760260 @default.
• W2884893670 cites W2951713858 @default.
• W2884893670 cites W803970747 @default.
• W2884893670 doi "https://doi.org/10.1021/acs.inorgchem.8b01261" @default.
• W2884893670 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30016088" @default.
• W2884893670 hasPublicationYear "2018" @default.
• W2884893670 type Work @default.
• W2884893670 sameAs 2884893670 @default.
• W2884893670 citedByCount "12" @default.
• W2884893670 countsByYear W28848936702019 @default.
• W2884893670 countsByYear W28848936702020 @default.
• W2884893670 countsByYear W28848936702021 @default.
• W2884893670 countsByYear W28848936702022 @default.
• W2884893670 countsByYear W28848936702023 @default.
• W2884893670 crossrefType "journal-article" @default.
• W2884893670 hasAuthorship W2884893670A5026155734 @default.
• W2884893670 hasAuthorship W2884893670A5026209005 @default.
• W2884893670 hasAuthorship W2884893670A5051847614 @default.
• W2884893670 hasAuthorship W2884893670A5058456003 @default.
• W2884893670 hasAuthorship W2884893670A5069807123 @default.
• W2884893670 hasConcept C11111787 @default.
• W2884893670 hasConcept C115624301 @default.
• W2884893670 hasConcept C120665830 @default.
• W2884893670 hasConcept C121332964 @default.
• W2884893670 hasConcept C145148216 @default.
• W2884893670 hasConcept C148869448 @default.
• W2884893670 hasConcept C178790620 @default.
• W2884893670 hasConcept C183882617 @default.
• W2884893670 hasConcept C185592680 @default.
• W2884893670 hasConcept C191952053 @default.
• W2884893670 hasConcept C26873012 @default.
• W2884893670 hasConcept C2779291638 @default.
• W2884893670 hasConcept C2779303976 @default.
• W2884893670 hasConcept C44280652 @default.
• W2884893670 hasConcept C54998646 @default.
• W2884893670 hasConcept C57863236 @default.
• W2884893670 hasConcept C62520636 @default.
• W2884893670 hasConcept C8010536 @default.
• W2884893670 hasConceptScore W2884893670C11111787 @default.
• W2884893670 hasConceptScore W2884893670C115624301 @default.
• W2884893670 hasConceptScore W2884893670C120665830 @default.
• W2884893670 hasConceptScore W2884893670C121332964 @default.
• W2884893670 hasConceptScore W2884893670C145148216 @default.
• W2884893670 hasConceptScore W2884893670C148869448 @default.
• W2884893670 hasConceptScore W2884893670C178790620 @default.
• W2884893670 hasConceptScore W2884893670C183882617 @default.
• W2884893670 hasConceptScore W2884893670C185592680 @default.
• W2884893670 hasConceptScore W2884893670C191952053 @default.
• W2884893670 hasConceptScore W2884893670C26873012 @default.
• W2884893670 hasConceptScore W2884893670C2779291638 @default.
• W2884893670 hasConceptScore W2884893670C2779303976 @default.
• W2884893670 hasConceptScore W2884893670C44280652 @default.
• W2884893670 hasConceptScore W2884893670C54998646 @default.
• W2884893670 hasConceptScore W2884893670C57863236 @default.
• W2884893670 hasConceptScore W2884893670C62520636 @default.
• W2884893670 hasConceptScore W2884893670C8010536 @default.
• W2884893670 hasFunder F4320322687 @default.
• W2884893670 hasFunder F4320322725 @default.
• W2884893670 hasFunder F4320323539 @default.
• W2884893670 hasIssue "15" @default.
• W2884893670 hasLocation W28848936701 @default.

• next