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- W2885181651 abstract "The phospha-Peterson reaction between a lithiated secondary phosphane, MesP(Li)TMS, and an aldehyde affords Mes-phosphaalkenes which, upon methanol addition and P-oxidation, react with a second carbonyl compound site specifically to produce unsymmetric alkenes. The E/Z selectivity of the one-pot cross coupling is largely determined by the electronic nature of the aryl substituent of the first aldehyde, with electron-donating groups giving rise to increased amounts of Z-alkenes." @default.
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- W2885181651 date "2018-08-13" @default.
- W2885181651 modified "2023-09-27" @default.
- W2885181651 title "One-Pot Intermolecular Reductive Cross-Coupling of Deactivated Aldehydes to Unsymmetrically 1,2-Disubstituted Alkenes" @default.
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- W2885181651 doi "https://doi.org/10.1021/acs.orglett.8b01754" @default.
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