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• W2885282048 endingPage "4994" @default.
• W2885282048 startingPage "4988" @default.
• W2885282048 abstract "Reaction pathways and kinetics in highly structured H2O adsorbed as Ångstrom to nanometer thick layers on mineral surfaces are distinct from those facilitated by bulk liquid water. We investigate the role of the interfacial H2O structure in the reaction of H2O and CO2 to form carbonic acid (H2CO3) in thin H2O films condensed onto silica nanoparticles from humidified supercritical CO2. Rates of carbonic acid formation are correlated with spectroscopic signatures of H2O structure using oxygen isotopic tracers and infrared spectroscopy. While carbonic acid virtually does not form in the supercritical phase, the silica surface catalyzes this reaction by concentrating H2O through adsorption at hydrophilic silanol groups. Within measurement uncertainty, we found no evidence that carbonic acid forms when exclusively ice-like structured H2O is detected at the silica surface. Instead, formation of H2C18O16O2 from H218O and C16O2 was found to be linearly correlated with liquid-like structured H2O that formed on the ice-like layer." @default.
• W2885282048 created "2018-08-22" @default.
• W2885282048 creator A5014746260 @default.
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• W2885282048 date "2018-08-14" @default.
• W2885282048 modified "2023-09-24" @default.
• W2885282048 title "Water Structure Controls Carbonic Acid Formation in Adsorbed Water Films" @default.
• W2885282048 cites W1968419973 @default.
• W2885282048 cites W1972642175 @default.
• W2885282048 cites W1973506949 @default.
• W2885282048 cites W1973786364 @default.
• W2885282048 cites W1976200513 @default.
• W2885282048 cites W1977279022 @default.
• W2885282048 cites W1983279622 @default.
• W2885282048 cites W1983534660 @default.
• W2885282048 cites W1989110589 @default.
• W2885282048 cites W1989761868 @default.
• W2885282048 cites W1990249941 @default.
• W2885282048 cites W1991967257 @default.
• W2885282048 cites W1994516383 @default.
• W2885282048 cites W1997080267 @default.
• W2885282048 cites W1997534665 @default.
• W2885282048 cites W2003277559 @default.
• W2885282048 cites W2005245888 @default.
• W2885282048 cites W2005374785 @default.
• W2885282048 cites W2006461080 @default.
• W2885282048 cites W2011263065 @default.
• W2885282048 cites W2013154170 @default.
• W2885282048 cites W2019069481 @default.
• W2885282048 cites W2022997587 @default.
• W2885282048 cites W2024349178 @default.
• W2885282048 cites W2024893196 @default.
• W2885282048 cites W2026967280 @default.
• W2885282048 cites W2028474154 @default.
• W2885282048 cites W2033614107 @default.
• W2885282048 cites W2034630914 @default.
• W2885282048 cites W2034759893 @default.
• W2885282048 cites W2034948128 @default.
• W2885282048 cites W2035334234 @default.
• W2885282048 cites W2040527150 @default.
• W2885282048 cites W2040805894 @default.
• W2885282048 cites W2042071946 @default.
• W2885282048 cites W2042303470 @default.
• W2885282048 cites W2043502390 @default.
• W2885282048 cites W2043800133 @default.
• W2885282048 cites W2045064685 @default.
• W2885282048 cites W2045465826 @default.
• W2885282048 cites W2046340127 @default.
• W2885282048 cites W2049995235 @default.
• W2885282048 cites W2053223604 @default.
• W2885282048 cites W2055199771 @default.
• W2885282048 cites W2057072218 @default.
• W2885282048 cites W2058098574 @default.
• W2885282048 cites W2065670737 @default.
• W2885282048 cites W2066236825 @default.
• W2885282048 cites W2066270086 @default.
• W2885282048 cites W2066398552 @default.
• W2885282048 cites W2069187694 @default.
• W2885282048 cites W2071673171 @default.
• W2885282048 cites W2073628878 @default.
• W2885282048 cites W2075828573 @default.
• W2885282048 cites W2079322542 @default.
• W2885282048 cites W2093840638 @default.
• W2885282048 cites W2095100718 @default.
• W2885282048 cites W2148242449 @default.
• W2885282048 cites W2167912038 @default.
• W2885282048 cites W2253555621 @default.
• W2885282048 cites W2261642263 @default.
• W2885282048 cites W2288704778 @default.
• W2885282048 cites W2303683068 @default.
• W2885282048 cites W2318691890 @default.
• W2885282048 cites W2322298765 @default.
• W2885282048 cites W2329633650 @default.
• W2885282048 cites W2340387005 @default.
• W2885282048 cites W2399084056 @default.
• W2885282048 cites W2417445437 @default.
• W2885282048 cites W2417977945 @default.
• W2885282048 cites W2466023164 @default.
• W2885282048 cites W2469980147 @default.
• W2885282048 cites W255890309 @default.
• W2885282048 cites W2575389640 @default.
• W2885282048 cites W2600740226 @default.
• W2885282048 cites W2757837025 @default.
• W2885282048 cites W2806318808 @default.
• W2885282048 cites W2883150550 @default.
• W2885282048 cites W3024302825 @default.
• W2885282048 cites W3100474188 @default.
• W2885282048 doi "https://doi.org/10.1021/acs.jpclett.8b02162" @default.
• W2885282048 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30107739" @default.
• W2885282048 hasPublicationYear "2018" @default.
• W2885282048 type Work @default.

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