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- W2885382890 abstract "A new and efficient oxidative coupling reaction between enoxysilane and alkylnitrile radicals derived from readily available AIBN and its analogues has been developed by using redox-active metal as a catalyst in which the redox-active copper is used for enhancing the electrophilicity of a free radical via coordination and bringing the radical and nucleophilic enol ether closer to facilitate the single-electron transfer. The present catalytic protocol afforded a variety of γ-ketonitriles in good to excellent yields with good functional group tolerance." @default.
- W2885382890 created "2018-08-22" @default.
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- W2885382890 date "2018-08-03" @default.
- W2885382890 modified "2023-09-26" @default.
- W2885382890 title "Copper-Catalyzed Oxidative Coupling of AIBN and Ketone-Derived Enoxysilanes to γ-Ketonitriles" @default.
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- W2885382890 doi "https://doi.org/10.1021/acs.orglett.8b02154" @default.
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