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- W2885404639 abstract "The twelve isotypic intermetallic compounds R2Ru3Ga9 with R = Y, La–Nd, Sm, Gd–Tm were prepared by arc-melting of the elemental components. Their crystal structure was determined from single-crystal X-ray data of Dy2Ru3Ga9: Cmcm, a = 1279.3(2) pm, b = 755.6(1) pm, c = 964.7(1) pm, Z = 4, R = 0.020 for 671 structure factors and 42 variable parameters. All atomic positions have within two standard deviations ideal occupancies (occupancy values vary between 98.8(5) and 101.2(6)%). The structure is briefly discussed, emphasizing its relation to other structures with a high content of gallium or aluminum. Seltenerdmetall–Ruthenium-Gallide R2Ru3Ga9 mit Y2Co3Ga9-Struktur Die zwölf isotypen intermetallischen Verbindungen R2Ru3Ga9 mit R = Y, La–Nd, Sm, Gd–Tm wurden im Lichtbogenofen aus den elementaren Komponenten hergestellt. Ihre Kristallstruktur wurde durch Einkristall-Röntgendiffraktometer-Daten von Dy2Ru3Ga9 bestimmt: Cmcm, a = 1279.3(2) pm, b = 755.6(1) pm, c = 964.7(1) pm, Z = 4, R = 0.020 für 671 Strukturfaktoren und 42 variable Parameter. Alle Atompositionen zeigen innerhalb der doppelten Standardabweichungen ideale Besetzung (Besetzungsparameter variieren zwischen 98.8(5) und 101.2(6)%). Die Struktur wird kurz diskutiert mit besonderem Augenmerk auf ähnliche Strukturen mit hohem Gallium- oder Aluminiumgehalt." @default.
- W2885404639 created "2018-08-22" @default.
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- W2885404639 date "2000-10-01" @default.
- W2885404639 modified "2023-09-25" @default.
- W2885404639 title "Rare Earth Metal Ruthenium GallidesR2Ru3Ga9 with Y2Co3Ga9 Type Structure" @default.
- W2885404639 doi "https://doi.org/10.1002/1521-3749(200010)626:10<2217::aid-zaac2217>3.0.co;2-b" @default.
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