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• W2885441144 endingPage "1952" @default.
• W2885441144 startingPage "1946" @default.
• W2885441144 abstract "ABSTRACT A conjugated crosslinked polyazomethine containing pyridine units ( PAM‐Py ) was prepared from two commercial monomers, 2,6‐diaminopyridine and isophthaldehyde, under microwave heating in only 30 min. Taking advantage of its thermal and chemical stability, porosity ( S BET of 192 m 2 /g), insolubility, and ability to coordinate metals through the pyridine or imine N atoms, ruthenium‐, aluminum‐, iron‐, and cobalt‐poly(azomethine‐pyridine) complexes ( PAM‐PyM ) were prepared. The resulting metal polymers were evaluated as heterogeneous catalysts for the cycloaddition of CO 2 to epoxides yielding selectively the corresponding cyclic carbonates. All heterogeneous catalysts showed an extraordinary effectiveness with very high yields of epoxide conversion (up to 98%), turnover numbers up to 7425, and were reused at least five times without loss in catalytic activity. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56 , 1946–1952" @default.
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• W2885441144 date "2018-08-09" @default.
• W2885441144 modified "2023-10-17" @default.
• W2885441144 title "Accessible microwave synthetized conjugated poly(azomethine-pyridine) network and its metal complexes for CO₂ conversion" @default.
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• W2885441144 doi "https://doi.org/10.1002/pola.29080" @default.
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