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• W2885497 abstract "The aggregation behavior and structure of hydrophobically modified block copolymers of acrylamide and 2-phenoxylethylacrylate were investigated by viscometry, 1 H NMR relaxation, 2D NOESY, fluorescence and dynamic light scattering. It was found that the aggregation behavior was strongly dependent on the concentration of polymer solution and the hydrophobe contents. With varying concentration from 2.0, 6.0, 8.0 to 12.0 g/L, there were different aggregate morphologies distributed in aqueous solutions, such as monopolymer chain, micelle-like aggregate, mul- ti-micelle aggregate and cross-linked network. According to the model of aggregation, it can give a reasonable ex- planation on the large magnitude enhancement of viscosity with the increasing of polymer concentration. Additional data of 2D NOESY and fluorescence show that the copolymer with higher hydrophobe content(molar fraction≥1%) is likely to form intra-molecular association. Keywords Aggregation behavior and structure; Hydrophobically modified; Copolymer P(AM/POEA) Article ID 1005-9040(2009)-06-957-06" @default.
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• W2885497 date "2009-01-01" @default.
• W2885497 modified "2023-09-23" @default.
• W2885497 title "Aggregation Behavior and Structure of Associated Polyacrylamide Hydrophobically Modified with 2-Phenoxylethylacrylate" @default.
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