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• W2885751725 abstract "Two chemosensors with varying substitution have been synthesized for selective detection of d10 metal ion analyte Zn2+ and Cd2+ by fluorometric method from aqueous medium at very low limit of detection. Density functional theory (DFT)-based Loewdin spin population analysis reveals that methoxy-substituted chemosensor is much stronger donor than bromo-substituted chemosensor. Eventually, bromo and methoxy substituted chemosensors are moderate and strong donor, respectively, toward selective detection of Cd2+ and Zn2+ by luminescence induced phenomenon (blue for Cd2+ and cyan for Zn2+). The mechanism of sensing could be explained by PET-CHEF-C = N isomerization-ILCT pathway. 1H NMR, ESI-MS and FT-IR has been carried out in order to explore the selective ion sensing mechanism. Intracellular detection of Zn2+ and Cd2+ has been carried out inside androecium (filament and pollens) of Tecoma Stans. Extracellular detection of Zn2+ for yeast cells represents the bio mimetic model experiments toward β-cells exocytosis as a marker of diabetes mellitus. The unprecedented and novel feature of the present biocompatible chemosensor is its application as biosensor to detect in vivo Zn2+ from human urine specimen which could be a next generation diagnostic tool for Pick's disease." @default.
• W2885751725 created "2018-08-22" @default.
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• W2885751725 date "2018-07-31" @default.
• W2885751725 modified "2023-10-09" @default.
• W2885751725 title "Trace Level Recognition of Zn²⁺ and Cd²⁺ by Biocompatible Chemosensor inside Androecium, Diagnosis of Pick’s Disease from Urine and Biomimetic β-Cell Exocytosis" @default.
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• W2885751725 doi "https://doi.org/10.1021/acsabm.8b00163" @default.
• W2885751725 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34996199" @default.
• W2885751725 hasPublicationYear "2018" @default.
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