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- W2885753083 endingPage "613" @default.
- W2885753083 startingPage "575" @default.
- W2885753083 abstract "Rate coefficients (k•OH) of hydroxyl radical + antibiotic molecule reactions (c.a. 200 k•OH values for 70 molecules) were collected from published studies. Data measured in different laboratories, occasionally by different methods, were compared. Excluding the rate coefficients with values above the diffusion controlled limit and adjusting rate coefficients determined by competition kinetics, the data were averaged and the most probable values were selected. Rate coefficients for compounds with aromatic rings (e.g., amoxicillin) or conjugated double bonds (e.g., tylosin) are in the (6 – 8) × 109 mol−1 dm3 s−1 range. The basic reaction is radical addition. The value may be smaller when strong electron withdrawing substituent, like –NO2 is attached to the ring, and N-atoms in the aromatic ring also reduce the rate coefficient. The rate coefficients for molecules without aromatic rings are smaller with values in the (3 – 6) × 109 mol−1 dm3 s−1 range, where hydrogen abstraction reactions dominate. Carefully executed pulse radiolysis and steady-state experiments (with correct reference values) give similar rate coefficients." @default.
- W2885753083 created "2018-08-22" @default.
- W2885753083 creator A5032324556 @default.
- W2885753083 creator A5045996715 @default.
- W2885753083 creator A5086568954 @default.
- W2885753083 date "2018-03-19" @default.
- W2885753083 modified "2023-09-30" @default.
- W2885753083 title "Critical evaluation of rate coefficients for hydroxyl radical reactions with antibiotics: A review" @default.
- W2885753083 cites W1498398265 @default.
- W2885753083 cites W1523313316 @default.
- W2885753083 cites W1669810599 @default.
- W2885753083 cites W1926950498 @default.
- W2885753083 cites W1969899546 @default.
- W2885753083 cites W1969934715 @default.
- W2885753083 cites W1972711235 @default.
- W2885753083 cites W1975626699 @default.
- W2885753083 cites W1976291432 @default.
- W2885753083 cites W1978440801 @default.
- W2885753083 cites W1980190163 @default.
- W2885753083 cites W1982887324 @default.
- W2885753083 cites W1983534609 @default.
- W2885753083 cites W1984646875 @default.
- W2885753083 cites W1986857781 @default.
- W2885753083 cites W1986933837 @default.
- W2885753083 cites W1990251051 @default.
- W2885753083 cites W1990504895 @default.
- W2885753083 cites W1990816240 @default.
- W2885753083 cites W1991071656 @default.
- W2885753083 cites W2000930279 @default.
- W2885753083 cites W2001682416 @default.
- W2885753083 cites W2002717121 @default.
- W2885753083 cites W2005466968 @default.
- W2885753083 cites W2006601958 @default.
- W2885753083 cites W2008469475 @default.
- W2885753083 cites W2013429473 @default.
- W2885753083 cites W2016865664 @default.
- W2885753083 cites W2016887717 @default.
- W2885753083 cites W2019859863 @default.
- W2885753083 cites W2022639638 @default.
- W2885753083 cites W2023453388 @default.
- W2885753083 cites W2030068809 @default.
- W2885753083 cites W2030934239 @default.
- W2885753083 cites W2031203039 @default.
- W2885753083 cites W2033553897 @default.
- W2885753083 cites W2034384897 @default.
- W2885753083 cites W2036545251 @default.
- W2885753083 cites W2037533040 @default.
- W2885753083 cites W2038640480 @default.
- W2885753083 cites W2041395691 @default.
- W2885753083 cites W2042732819 @default.
- W2885753083 cites W2045043410 @default.
- W2885753083 cites W2045538116 @default.
- W2885753083 cites W2045969791 @default.
- W2885753083 cites W2048693902 @default.
- W2885753083 cites W2052564560 @default.
- W2885753083 cites W2053550496 @default.
- W2885753083 cites W2053941895 @default.
- W2885753083 cites W2056113567 @default.
- W2885753083 cites W2056428829 @default.
- W2885753083 cites W2056593643 @default.
- W2885753083 cites W2058986864 @default.
- W2885753083 cites W2059598963 @default.
- W2885753083 cites W2060160419 @default.
- W2885753083 cites W2067628213 @default.
- W2885753083 cites W2068119928 @default.
- W2885753083 cites W2068792635 @default.
- W2885753083 cites W2072513400 @default.
- W2885753083 cites W2073454645 @default.
- W2885753083 cites W2080079641 @default.
- W2885753083 cites W2081014787 @default.
- W2885753083 cites W2083764259 @default.
- W2885753083 cites W2087705055 @default.
- W2885753083 cites W2091200408 @default.
- W2885753083 cites W2108079322 @default.
- W2885753083 cites W2113790776 @default.
- W2885753083 cites W2119622056 @default.
- W2885753083 cites W2129131152 @default.
- W2885753083 cites W2133078278 @default.
- W2885753083 cites W2133355361 @default.
- W2885753083 cites W2148739453 @default.
- W2885753083 cites W2160165060 @default.
- W2885753083 cites W2171344290 @default.
- W2885753083 cites W2185055687 @default.
- W2885753083 cites W2202032113 @default.
- W2885753083 cites W221812182 @default.
- W2885753083 cites W2228038983 @default.
- W2885753083 cites W2248778963 @default.
- W2885753083 cites W2252521324 @default.
- W2885753083 cites W2258104330 @default.
- W2885753083 cites W2312947310 @default.
- W2885753083 cites W2317842563 @default.
- W2885753083 cites W2321605778 @default.
- W2885753083 cites W2332236699 @default.
- W2885753083 cites W2346060623 @default.
- W2885753083 cites W2497090112 @default.
- W2885753083 cites W2505689076 @default.
- W2885753083 cites W2506589090 @default.
- W2885753083 cites W2509519937 @default.