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- W2885803640 abstract "Here, we report synthesis and properties of a di-ruthenium acetylide molecular wire having a diethynylporphyrinatomanganese linker, and the effect of the coordination of electron-donor molecules to the Mn center on the metal-metal interaction is also described. Electrochemical and spectroscopic studies of the wire reveal highly charge delocalized properties. Addition of pyridine in the presence of [NBu4][PF6] causes electrochemical and spectroscopic changes, suggesting modulation of the ruthenium-ruthenium interaction. On the basis of a DFT study, the formation of a cationic bis-pyridine adduct has been confirmed to play a key role in the modulaion. Here, we report synthesis and properties of a di-ruthenium acetylide molecular wire having a manganese porphyrin linker. Electrochemical and spectroscopic studies of the wire reveal highly charge delocalized properties. Addition of pyridine in the presence of [NBu4][PF6] causes electrochemical and spectroscopic changes, suggesting modulation of the ruthenium-ruthenium interaction." @default.
- W2885803640 created "2018-08-22" @default.
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- W2885803640 date "2018-10-05" @default.
- W2885803640 modified "2023-10-14" @default.
- W2885803640 title "An Organometallic Molecular Wire Bearing a Manganese Porphyrin Linker: Coordination-driven Modulation of the Metal-Metal Interaction" @default.
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- W2885803640 doi "https://doi.org/10.1246/cl.180592" @default.
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