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- W2885819306 abstract "The relativistic correction to the dissociation energy of H_{2}, D_{2}, and HD molecules has been accurately calculated without expansion in the small electron-nucleus mass ratio. The obtained results indicate the significance of nonadiabatic effects and resolve the discrepancy of theoretical predictions with recent experimental values for H_{2} and D_{2}. While the theoretical accuracy is now significantly improved and is higher than the experimental one, we observe about 3σ discrepancy for the dissociation energy of HD, which requires further investigation." @default.
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- W2885819306 date "2018-08-14" @default.
- W2885819306 modified "2023-10-18" @default.
- W2885819306 title "Nonadiabatic Relativistic Correction to the Dissociation Energy of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>H</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math> , <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>D</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub…" @default.
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- W2885819306 doi "https://doi.org/10.1103/physrevlett.121.073001" @default.
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