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- W2885877221 abstract "Abstract Ni‐rich layered compounds are very promising cathodes for lithium ion batteries whose surface modifications are normally required. As excellent lithium‐conducting solid electrolytes lithium aluminates such as LiAlO 2 are expected to have an important role to play as a candidate for surface modifications. Here, Ni‐rich layered LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM) coated by lithium aluminates with different nominal weight percentages was prepared using a sol‐gel method. Lithium aluminates are found to be a mixture of major LiAlO 2 and minor Li 5 AlO 4 . The coatings almost have no influence on the size and morphology of NCM particles, and however favor the order degree of structure and change the surface states. The electrical conductivity and charge transfer resistance can be optimized by controlling the amount of lithium aluminates. The cycling stability at low rates such as 1 C tends to increase with the amount of lithium aluminates whereas the rate capability can be achieved at certain amount, which is probably related to the enhancement of electrical conductivity and the improved surface protection against the erosion by electrolyte. This study reveals that the performances of NCM can be significantly improved and tailored by controlling the amount of lithium aluminates." @default.
- W2885877221 created "2018-08-22" @default.
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- W2885877221 date "2018-11-23" @default.
- W2885877221 modified "2023-09-25" @default.
- W2885877221 title "Improvement of Electrochemical Performance of Nickel Rich LiNi<sub>0.8</sub> Co<sub>0.1</sub> Mn<sub>0.1</sub> O<sub>2</sub> Cathode by Lithium Aluminates Surface Modifications" @default.
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- W2885877221 doi "https://doi.org/10.1002/ente.201800506" @default.
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