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• W2885893758 startingPage "8318" @default.
• W2885893758 abstract "A highly enantioselective Cu(II)-catalyzed borylative reaction of β-trifluoromethyl β,β-disubstituted enones was developed, which provide a facile access to a variety of chiral alkylboronic esters with a quaternary stereocenter including both a trifluoromethyl group and a boron group. Meanwhile, CF3-contained tertiary alcohol derivatives were obtained in high yield with the maintained ee value via one-pot methodology. The reactions proceed smoothly under mild reaction conditions, providing expedient access to construct chiral alkylboronic esters in well-functional group tolerances, good yields, diversity conversion, and high enantioselectivities. The appropriate SDE test via achiral chromatography illustrated that the results presented here were reliable." @default.
• W2885893758 created "2018-08-22" @default.
• W2885893758 creator A5046202330 @default.
• W2885893758 creator A5061807881 @default.
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• W2885893758 date "2018-08-06" @default.
• W2885893758 modified "2023-10-18" @default.
• W2885893758 title "Cu(II)-Catalyzed Enantioselective β-Boration of β-Trifluoromethyl, β,β-Disubstituted Enones and Esters: Construction of a CF₃- and Boron-Containing Quaternary Stereocenter" @default.
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• W2885893758 doi "https://doi.org/10.1021/acscatal.8b02543" @default.
• W2885893758 hasPublicationYear "2018" @default.
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