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• W2885978008 abstract "The effect of P-providing components (phosphorous acid, H3PO3 and sodium hypophosphite, NaH2PO2) in modified Watts electrolyte (pH = 2; 80 °C) on the barrier ability and durability of the deposited NiCoP and NiCo (as a reference) coatings during extended exposure in 3.5% NaCl until 672 h was studied. The data acquired for the charge transfer and polarization resistances (Rct and Rp) by electrochemical impedance spectroscopy, EIS and linear voltammetry, LVA, undoubtedly reveal that the best corrosion protective properties belong to the NiCoP coating deposited at simultaneous occurrence of H3PO3 and NaH2PO2. It was followed subsequently by those obtained from electrolyte with only NaH2PO2, then, deposited from electrolyte with only H3PO3 and finally by the reference NiCo coating. The occurrence of an amorphous phase in the structure of NiCoP coatings, combined with the increase of cobalt content and reducing that of nickel, predetermines the best protective properties of the investigated alloys. The established anomalous Rct and Rp increment during the exposure of NiCoP coatings could be related to corrosion products accumulation, most probably of metal phosphates, and it forms a barrier layer between the coating and the corrosive medium." @default.
• W2885978008 created "2018-08-22" @default.
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• W2885978008 date "2018-11-01" @default.
• W2885978008 modified "2023-09-26" @default.
• W2885978008 title "Barrier ability and durability of Ni Co P coatings in accordance to the content of H3PO3 and NaH2PO2 as phosphorus sources" @default.
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• W2885978008 doi "https://doi.org/10.1016/j.matchemphys.2018.08.025" @default.
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