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• W2885995712 abstract "We report an efficient Pd(0)-catalyzed deacylative allylation of N-acyl 3-substituted 2-oxindoles via the coupling of in situ generated nucleophiles (3 and 4) with allyl electrophiles for the synthesis of a variety of 2-oxindoles with C3-quaternary centers. Gratifyingly, this alkylation process is found to be highly chemoselective in nature, where a C–C bond formation is completely predominant over a C–N bond formation. A variety of key intermediates were synthesized utilizing an aforementioned methodology." @default.
• W2885995712 created "2018-08-22" @default.
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• W2885995712 date "2018-07-30" @default.
• W2885995712 modified "2023-09-26" @default.
• W2885995712 title "Pd(0)-Catalyzed Chemoselective Deacylative Alkylations (DaA) of <i>N</i>-Acyl 2-Oxindoles: Total Syntheses of Pyrrolidino[2,3-<i>b</i>]indoline Alkaloids, (±)-Deoxyeseroline, and (±)-Esermethole" @default.
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• W2885995712 doi "https://doi.org/10.1021/acs.joc.8b01101" @default.
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