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• W2886239698 abstract "A practical and asymmetric synthesis of a small-molecule CXCR7 modulator featuring a highly functionalized and hindered tertiary β-amino amide framework is reported. The cornerstone of this strategy relied on the intermediacy of a reactive aziridinium species, which, following regioselective ring opening with cyanide, furnished the desired chiral β-tertiary amino nitrile for further elaboration. As a means of further highlighting this synthetic strategy, an expanded scope of hindered β-amino amide synthesis is also presented." @default.
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• W2886239698 date "2018-08-17" @default.
• W2886239698 modified "2023-10-09" @default.
• W2886239698 title "Asymmetric Synthesis of a Potent CXCR7 Modulator Featuring a Hindered Tertiary β-Amino Amide Stereocenter" @default.
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• W2886239698 doi "https://doi.org/10.1021/acs.orglett.8b02261" @default.
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