Matches in SemOpenAlex for { <https://semopenalex.org/work/W2886256321> ?p ?o ?g. }
- W2886256321 endingPage "456" @default.
- W2886256321 startingPage "447" @default.
- W2886256321 abstract "The copper(II) complexes [Cu4(L)2(HL)2(H2O)2]∙2(ClO4)∙2(H2O)∙DMF (1) and [Cu4(L)2(HL)2(H2O)2]∙(tp) (2) [H2L = 2-ethoxy-6-[(1-hydroxymethyl-propylimino)-methyl]-phenol; tp = terephthalate] have been synthesized and characterized by single crystal X-ray diffraction and spectroscopic studies. The structural determination reveals that both the complexes are tetranuclear with a double-open-cubane like core framework. The 2D supramolecular structure of 1 and 3D supramolecular structure of 2 are formed through C–H…π and hydrogen bonding interactions, respectively. At room temperature both the complexes exhibit fluorescence with quantum yields of 0.41 and 0.40. The interactions of the complexes with calf thymus DNA (CT-DNA) and serum albumins were investigated using electronic absorption and fluorescence spectroscopic techniques. The studies revels that the binding affinities of 1 and 2 with CT-DNA are of the order 8.86 × 105 M−1 and 7.14 × 105 M−1, respectively. Additionally, the interaction of the complexes with bovine serum albumin and human serum albumin were studied and the number of binding sites and binding constants were calculated using a double logarithm regression equation. The redox activities of the complexes were investigated in methanol solution by cyclic voltammetry." @default.
- W2886256321 created "2018-08-22" @default.
- W2886256321 creator A5009567659 @default.
- W2886256321 creator A5048450819 @default.
- W2886256321 creator A5076789541 @default.
- W2886256321 date "2018-11-01" @default.
- W2886256321 modified "2023-09-30" @default.
- W2886256321 title "Synthesis, crystal structure and DNA/protein binding of tetranuclear Cu(II) complexes with a double-open-cubane like core framework" @default.
- W2886256321 cites W1483890119 @default.
- W2886256321 cites W1948068257 @default.
- W2886256321 cites W1963605029 @default.
- W2886256321 cites W1963875686 @default.
- W2886256321 cites W1964551188 @default.
- W2886256321 cites W1973153850 @default.
- W2886256321 cites W1975015655 @default.
- W2886256321 cites W1975153728 @default.
- W2886256321 cites W1975165348 @default.
- W2886256321 cites W1981006942 @default.
- W2886256321 cites W1984781269 @default.
- W2886256321 cites W1987770897 @default.
- W2886256321 cites W1988205388 @default.
- W2886256321 cites W1993826580 @default.
- W2886256321 cites W1997368175 @default.
- W2886256321 cites W1998397457 @default.
- W2886256321 cites W2000964158 @default.
- W2886256321 cites W2002199178 @default.
- W2886256321 cites W2002845466 @default.
- W2886256321 cites W2003221148 @default.
- W2886256321 cites W2011889872 @default.
- W2886256321 cites W2012108057 @default.
- W2886256321 cites W2012245327 @default.
- W2886256321 cites W2020185130 @default.
- W2886256321 cites W2025599517 @default.
- W2886256321 cites W2025999318 @default.
- W2886256321 cites W2027140236 @default.
- W2886256321 cites W2036098386 @default.
- W2886256321 cites W2038114800 @default.
- W2886256321 cites W2043624888 @default.
- W2886256321 cites W2044851985 @default.
- W2886256321 cites W2048925647 @default.
- W2886256321 cites W2049923510 @default.
- W2886256321 cites W2051187290 @default.
- W2886256321 cites W2052562606 @default.
- W2886256321 cites W2055206087 @default.
- W2886256321 cites W2055324972 @default.
- W2886256321 cites W2059012433 @default.
- W2886256321 cites W2059205366 @default.
- W2886256321 cites W2059513289 @default.
- W2886256321 cites W2063334178 @default.
- W2886256321 cites W2070344868 @default.
- W2886256321 cites W2071001197 @default.
- W2886256321 cites W2073378339 @default.
- W2886256321 cites W2074078791 @default.
- W2886256321 cites W2078139505 @default.
- W2886256321 cites W2078609269 @default.
- W2886256321 cites W2081048082 @default.
- W2886256321 cites W2082728813 @default.
- W2886256321 cites W2087010581 @default.
- W2886256321 cites W2101999088 @default.
- W2886256321 cites W2105249240 @default.
- W2886256321 cites W2108950213 @default.
- W2886256321 cites W2109741335 @default.
- W2886256321 cites W2110008743 @default.
- W2886256321 cites W2111692492 @default.
- W2886256321 cites W2126754043 @default.
- W2886256321 cites W2128597892 @default.
- W2886256321 cites W2131350133 @default.
- W2886256321 cites W2157986221 @default.
- W2886256321 cites W2161402983 @default.
- W2886256321 cites W2161986640 @default.
- W2886256321 cites W2163411926 @default.
- W2886256321 cites W2166591911 @default.
- W2886256321 cites W2182770127 @default.
- W2886256321 cites W2220680100 @default.
- W2886256321 cites W2312812994 @default.
- W2886256321 cites W2313813764 @default.
- W2886256321 cites W2314382662 @default.
- W2886256321 cites W2319170265 @default.
- W2886256321 cites W2329396091 @default.
- W2886256321 cites W2332851868 @default.
- W2886256321 cites W2335217555 @default.
- W2886256321 cites W2341069136 @default.
- W2886256321 cites W2344984955 @default.
- W2886256321 cites W2346343631 @default.
- W2886256321 cites W234665607 @default.
- W2886256321 cites W2411051660 @default.
- W2886256321 cites W2523377676 @default.
- W2886256321 cites W2565310970 @default.
- W2886256321 cites W2588243477 @default.
- W2886256321 cites W2606940046 @default.
- W2886256321 cites W2619405227 @default.
- W2886256321 cites W2781765147 @default.
- W2886256321 cites W2796520515 @default.
- W2886256321 cites W2884773953 @default.
- W2886256321 cites W2888099200 @default.
- W2886256321 doi "https://doi.org/10.1016/j.poly.2018.08.020" @default.
- W2886256321 hasPublicationYear "2018" @default.
- W2886256321 type Work @default.