FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2886439866> ?p ?o ?g. }

• W2886439866 endingPage "11077" @default.
• W2886439866 startingPage "11070" @default.
• W2886439866 abstract "A simple, safe, and sensitive method for direct multielemental trace determinations in plutonium samples using total reflection X-ray fluorescence (TXRF) spectrometry has been developed. A very small volume (2 μL) of the sample solutions was deposited on TXRF supports after separation of the plutonium matrix from these solutions. Since the amount of the plutonium deposited on the supports was in the ng level only fixed on the supports and the specimen spots were not disturbed during the sample preparation, the samples could be analyzed directly without putting the instrument in a glovebox. This approach avoided a cumbersome operation of the instrument in a glovebox, which is normally utilized for Pu-based samples using other techniques. Similarly, the requirement of small amounts of the samples minimized the radiation dose to the operator as well as a cumbersome problem of management of radioactive analytical waste of plutonium samples. The samples were analyzed using the TXRF spectra of the specimens, concentration of the internal standard Se or Ga and predetermined sensitivity values. The elemental detection limits for the elements K–Sr varied from 1.06 to 0.09 ng. The elements K, Ca, Cr, Mn, Fe, Ni, Cu, Zn, Sr, Ba, Tl, and Pb were analyzed at μg/mL level. The analytical results of TXRF determinations showed average relative standard deviation (RSD) value of 4.5% (1σ, n = 3) and the TXRF determined results deviated from the expected values by 5.9% on average for samples prepared by adding multielements in plutonium solutions. Two real plutonium samples were also analyzed in similar manner. For the real plutonium sample solution the average RSD values of TXRF determinations were 10.6% (1σ, n = 3) for the elemental concentrations in the range of 0.2 to 61 μg/mL. These values are comparable with conventional trace element analytical techniques with added advantages mentioned above." @default.
• W2886439866 created "2018-08-22" @default.
• W2886439866 creator A5003768446 @default.
• W2886439866 creator A5033103793 @default.
• W2886439866 creator A5035546284 @default.
• W2886439866 date "2018-08-09" @default.
• W2886439866 modified "2023-09-26" @default.
• W2886439866 title "Direct Multielemental Trace Determinations in Plutonium Samples by Total Reflection X-ray Fluorescence Spectrometry Using a Very Small Sample Amount" @default.
• W2886439866 cites W1523164231 @default.
• W2886439866 cites W1639802872 @default.
• W2886439866 cites W1939365332 @default.
• W2886439866 cites W1986348437 @default.
• W2886439866 cites W2013858881 @default.
• W2886439866 cites W2026906585 @default.
• W2886439866 cites W2028070757 @default.
• W2886439866 cites W2028121821 @default.
• W2886439866 cites W2032558453 @default.
• W2886439866 cites W2039959034 @default.
• W2886439866 cites W2043339911 @default.
• W2886439866 cites W2049106170 @default.
• W2886439866 cites W2053938335 @default.
• W2886439866 cites W2060802794 @default.
• W2886439866 cites W2072683824 @default.
• W2886439866 cites W2073481580 @default.
• W2886439866 cites W2075146389 @default.
• W2886439866 cites W2086840194 @default.
• W2886439866 cites W2089017597 @default.
• W2886439866 cites W2121526039 @default.
• W2886439866 cites W2123548123 @default.
• W2886439866 cites W2414105767 @default.
• W2886439866 cites W2798109202 @default.
• W2886439866 doi "https://doi.org/10.1021/acs.analchem.8b02917" @default.
• W2886439866 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30091364" @default.
• W2886439866 hasPublicationYear "2018" @default.
• W2886439866 type Work @default.
• W2886439866 sameAs 2886439866 @default.
• W2886439866 citedByCount "8" @default.
• W2886439866 countsByYear W28864398662019 @default.
• W2886439866 countsByYear W28864398662020 @default.
• W2886439866 countsByYear W28864398662021 @default.
• W2886439866 countsByYear W28864398662023 @default.
• W2886439866 crossrefType "journal-article" @default.
• W2886439866 hasAuthorship W2886439866A5003768446 @default.
• W2886439866 hasAuthorship W2886439866A5033103793 @default.
• W2886439866 hasAuthorship W2886439866A5035546284 @default.
• W2886439866 hasConcept C113196181 @default.
• W2886439866 hasConcept C121332964 @default.
• W2886439866 hasConcept C162170617 @default.
• W2886439866 hasConcept C162356407 @default.
• W2886439866 hasConcept C177322064 @default.
• W2886439866 hasConcept C178790620 @default.
• W2886439866 hasConcept C185592680 @default.
• W2886439866 hasConcept C2778576202 @default.
• W2886439866 hasConcept C2994048982 @default.
• W2886439866 hasConcept C43617362 @default.
• W2886439866 hasConcept C502230775 @default.
• W2886439866 hasConcept C5379308 @default.
• W2886439866 hasConcept C540271850 @default.
• W2886439866 hasConcept C62520636 @default.
• W2886439866 hasConcept C91881484 @default.
• W2886439866 hasConceptScore W2886439866C113196181 @default.
• W2886439866 hasConceptScore W2886439866C121332964 @default.
• W2886439866 hasConceptScore W2886439866C162170617 @default.
• W2886439866 hasConceptScore W2886439866C162356407 @default.
• W2886439866 hasConceptScore W2886439866C177322064 @default.
• W2886439866 hasConceptScore W2886439866C178790620 @default.
• W2886439866 hasConceptScore W2886439866C185592680 @default.
• W2886439866 hasConceptScore W2886439866C2778576202 @default.
• W2886439866 hasConceptScore W2886439866C2994048982 @default.
• W2886439866 hasConceptScore W2886439866C43617362 @default.
• W2886439866 hasConceptScore W2886439866C502230775 @default.
• W2886439866 hasConceptScore W2886439866C5379308 @default.
• W2886439866 hasConceptScore W2886439866C540271850 @default.
• W2886439866 hasConceptScore W2886439866C62520636 @default.
• W2886439866 hasConceptScore W2886439866C91881484 @default.
• W2886439866 hasFunder F4320334966 @default.
• W2886439866 hasIssue "18" @default.
• W2886439866 hasLocation W28864398661 @default.
• W2886439866 hasLocation W28864398662 @default.
• W2886439866 hasOpenAccess W2886439866 @default.
• W2886439866 hasPrimaryLocation W28864398661 @default.
• W2886439866 hasRelatedWork W1582389219 @default.
• W2886439866 hasRelatedWork W1996936725 @default.
• W2886439866 hasRelatedWork W2089339438 @default.
• W2886439866 hasRelatedWork W2159789625 @default.
• W2886439866 hasRelatedWork W2221902476 @default.
• W2886439866 hasRelatedWork W2358074263 @default.
• W2886439866 hasRelatedWork W2367458934 @default.
• W2886439866 hasRelatedWork W2369704718 @default.
• W2886439866 hasRelatedWork W2386923688 @default.
• W2886439866 hasRelatedWork W2886439866 @default.
• W2886439866 hasVolume "90" @default.
• W2886439866 isParatext "false" @default.
• W2886439866 isRetracted "false" @default.
• W2886439866 magId "2886439866" @default.
• W2886439866 workType "article" @default.