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• W2886494387 abstract "We report on electric dipoles induced by magnetic ion $mathrm{C}{mathrm{r}}^{3+}(3{d}^{3})$ off-center displacement with potential strong magnetoelectric coupling in simple perovskite $mathrm{DyCr}{mathrm{O}}_{3}$ crystals. $mathrm{DyCr}{mathrm{O}}_{3}$ was found to show quantum paraelectric behavior and the existence of electrical dipoles, as revealed by the dielectric, Raman scattering, and x-ray absorption near-edge structure spectra experiments. The anomalous lattice volume decreasing rate at low temperatures might play an important role in the $mathrm{C}{mathrm{r}}^{3+}$ ion displacement induced polar instability in $mathrm{DyCr}{mathrm{O}}_{3}$ as predicted by previous theoretical calculations. Our results on $mathrm{DyCr}{mathrm{O}}_{3}$ provide important experimental evidence for non-${d}^{0}$ transition-metal ion displacement induced electric dipoles, and they may lead to the exploration of multiferroics in a wider range of materials, especially magnetic perovskites." @default.
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• W2886494387 date "2018-08-02" @default.
• W2886494387 modified "2023-10-15" @default.
• W2886494387 title "Electric dipoles via <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi mathvariant=normal>C</mml:mi><mml:msup><mml:mrow><mml:mi mathvariant=normal>r</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup><mml:mrow><mml:mo>(</mml:mo><mml:msup><mml:mi>d</mml:mi><mml:mn>3</mml:mn></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:mrow></mml:math> ion off-center displacement in perovskite <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML…" @default.
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• W2886494387 doi "https://doi.org/10.1103/physrevb.98.054301" @default.
• W2886494387 hasPublicationYear "2018" @default.
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