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- W2886722196 abstract "We present the results of a detailed investigation of magnetism in spinel chromite NiCr2O4 magnetic nanoparticles (MNPs). Compared to the bulk NiCr2O4, the finite crystallite size of about 10 nm lowers the Jahn-Teller distortion and greatly enhances the collinearity of the spin structure in MNPs with considerably reduced “frustration index” = |θCW|/Tc. This leads to (longitudinal) ferrimagnetic ordering at much higher temperature, Tc≈100 K and suppression of (transverse) antiferromagnetic ordering in MNPs (cf. Tc ≃ 65 K and Ts ≃ 30 K in the bulk); a transition to the cluster spin glass state occurs at Tg = 19.0 K. Moreover, the M-H hysteresis loops show anomalous “hour-glass” behavior at fields near Hc in the vicinity of Tg; this non-monotonous Hc (T) variation can not be accounted from the celebrated Stoner-Wohlfarth model. The present study interprets the anomalous Hc (T) behavior in the framework of magnetically interacting core-shell structure with large surface anisotropy, and points out the importance of surface effects in nanochromites compared to their counterpart ferrites." @default.
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- W2886722196 date "2019-03-01" @default.
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- W2886722196 title "Anomalous nano-magnetic effects in non-collinear spinel chromite <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si3.gif overflow=scroll><mml:mrow><mml:msub><mml:mrow><mml:mtext>NiCr</mml:mtext></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si4.gif overflow=scroll><mml:mrow><mml:msub><mml:mrow><mml:mtext>O</mml:mtext></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:…" @default.
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- W2886722196 doi "https://doi.org/10.1016/j.jmmm.2018.08.037" @default.
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