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- W2886880991 abstract "Abstract Two novel bipyridinium-based metal–organic frameworks Zn[(pbpy)0.5(m-BDC)Cl]·1.5H2O(1) and Cd[(pbpy)0.5(m-BDC)Cl]·H2O(2).(pbpycl2 = 1,1′-[1,4-phenylenebis-(methylene)]bis(4,4′-bipyridinium)–dichloride) have been synthesized and structurally characterized by single crystal X-ray crystallography. Both of them show 2D layered window structures. When they are irradiated by 300 W Xenon lamp, both of them exhibit photochromic behaviors which are attributed to the process of intermolecular electron transfer to generate pbpycl2 free radicals. These processes have been demonstrated by UV–Vis absorption characterization analysis, electron spin resonance (ESR). The photoproduct of compound 1 is more stable than compound 2 in air. Photochromic mechanisms and the relationships between structures and properties have been discussed adequately." @default.
- W2886880991 created "2018-08-22" @default.
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- W2886880991 date "2018-10-01" @default.
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- W2886880991 title "Two cases of bipyridinium-based metal-organic frameworks: Syntheses, structures, photochromic behaviors" @default.
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- W2886880991 doi "https://doi.org/10.1016/j.inoche.2018.08.006" @default.
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