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- W2887029508 abstract "Abstract The monometallic five coordinated ruthenium(II) Schiff base complexes of the general type [Ru(CO)(EPh 3 ) 2 (L 1−3 )]Cl (E=P or As) have been synthesized and characterized by analytical and spectral (FT−IR, UV−Vis and 1 H NMR) methods. The electronic spectra of the complexes indicate the presence of intense MLCT transitions in the visible region. The molecular structure of the complex [Ru(CO)(PPh 3 ) 2 (L 3 )]Cl 5 was characterized by single crystal X−ray diffraction studies, which revealed that the Schiff base ligands coordinated to the ruthenium(II) ion as mono anionic bidentate (O, N) donor forming six membered chelating rings. Further, the five coordinate [Ru(CO)(PPh 3 ) 2 (L 3 )]Cl 5 complex was found efficiently to catalyze the formation of amides from various substituted aldehyde and showing higher catalytic activity in the presence of NH 2 OH.HCl and NaHCO 3 and the yield was up to 97%." @default.
- W2887029508 created "2018-08-22" @default.
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- W2887029508 date "2018-08-20" @default.
- W2887029508 modified "2023-10-14" @default.
- W2887029508 title "New Five Coordinate Ru(II) Carbonyl Complexes Containing 2-Aminofluorene Schiff Base Derivatives: Synthesis, Structure and Catalytic Activity" @default.
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- W2887029508 doi "https://doi.org/10.1002/slct.201801643" @default.
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