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- W2887030914 abstract "Abstract The low-temperature oxidation of 1,2,4-trimethylcyclohexane (T124MCH) as a representative of cyclohexanes was studied in a jet-stirred reactor at temperatures ranging between 600 and 1100 K, φ = 0.4 and 2.0. Mole fraction profiles of 28 species were obtained with online GC and GC–MS techniques. Based on the experimental observations and new calculations of the rate constants for the H-abstractions from the methyl groups of T124MCH by H/OH, a new kinetic model involving 530 species and 3160 reactions was developed with a reasonable agreement with the measured species profiles. With φ increasing, T124MCH consumption shifts to higher temperatures, and the reaction zone becomes broader by 50 K. Rate-of-production analysis reveals that T124MCH consumption is generally governed by C H bond cleavage to form nine cyclic C9H17 radicals, which mostly isomerize to linear C9H17 radicals and then decompose by β-scission. Sensitivity analysis reveals that reactions related to C2H3 and C3H6 play important roles in the consumption of T124MCH. Compared to cyclohexane, n-propylcyclohexane and 1,2,4-trimethylbenzene, T124MCH is the most comprehensive fuel which could produce obvious concentrations of hydrocarbon, aromatic, and oxidized intermediates. These results could improve the understanding of the oxidation process of T124MCH as a surrogate compound for kerosene and diesel to release the active intermediates and soot precursors." @default.
- W2887030914 created "2018-08-22" @default.
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- W2887030914 date "2019-01-01" @default.
- W2887030914 modified "2023-09-24" @default.
- W2887030914 title "An experimental and modeling study of oxidation of 1,2,4-trimethylcyclohexane with JSR" @default.
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- W2887030914 doi "https://doi.org/10.1016/j.proci.2018.07.029" @default.
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