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- W2887037467 abstract "Abstract The cis- and trans-potassium bis(oxalato)diaquochromates(III) have been studied towards their catalytic activity for the 2-chloroallyl alcohol oligomerization. The geometric isomerism effect on the oligomerization products under mild reaction conditions has been investigated. The molecular masses and tactic structures of obtained poly(2-chloroallyl alcohols) have been compared and analyzed. The mechanisms of oligomerization processes have been proposed. It has been proven that two studied complexes – cis-(hbox {K}[hbox {Cr}(hbox {C}_{2}hbox {O}_{4})_{2}(hbox {OH}_{2})_{2}]) and trans-(hbox {K}[hbox {Cr}(hbox {C}_{2}hbox {O}_{4})_{2}(hbox {OH}_{2})_{2}]cdot hbox {3H}_{2}hbox {O}) are highly active catalysts for the oligomerization of the beta-olefin derivative. Graphical Abstract SYNOPSIS: The investigations show the catalytic activity of cis- and trans-potassium bis(oxalato)diaquochromates(III) for the 2-chloroallyl alcohol oligomerization. The geometric isomerism effect in the bis(oxalato)diaquochromates(III) has been analyzed for the values of the catalytic activity of the synthesized complexes and the identity of the oligomerization products." @default.
- W2887037467 created "2018-08-22" @default.
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- W2887037467 date "2018-08-10" @default.
- W2887037467 modified "2023-09-24" @default.
- W2887037467 title "Geometric isomerism effect on catalytic activities of bis(oxalato)diaquochromates(III) for 2-chloroallyl alcohol oligomerization" @default.
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- W2887037467 doi "https://doi.org/10.1007/s12039-018-1515-3" @default.
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