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• W2887087718 abstract "A cobalt/POL-PPh3 catalyzed (E)-selective hydrosilylation of alkynes with PhSiH3 has been developed for the synthesis of (E)-β-vinylsilanes with high regio- and stereoselectivity and wide functional group tolerance. It is the first report of using porous organic polymer as a recyclable regio- and stereoselective and efficient ligand in hydrosilylation reactions in which the polymer could be recycled numerous times in a continuous flow system without loss of activity and selectivity. The earth-abundant base-metal catalyst, coordinated by heterogeneous recyclable ligand, shows promise for industrial application." @default.
• W2887087718 created "2018-08-22" @default.
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• W2887087718 date "2018-07-31" @default.
• W2887087718 modified "2023-10-13" @default.
• W2887087718 title "Highly Regio- and Stereoselective Heterogeneous Hydrosilylation of Terminal Alkynes over Cobalt-Metalated Porous Organic Polymer" @default.
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• W2887087718 doi "https://doi.org/10.1021/acs.orglett.8b02176" @default.
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