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• W2887119438 startingPage "887" @default.
• W2887119438 abstract "The chain length distribution (CLD) of a reversible deactivation radical polymerization at full conversion is shown to be a negative binomial distribution with parameters that are simple functions of the number-average degree of polymerization and either the chain transfer constant (in the case of polymerizations that incorporate a reversible chain transfer step) or the concentrations of dormant polymer chains and deactivating agent and the rate constants of propagation and deactivation (other types of RDRP). Expressions for the CLD at intermediate conversions are also derived, and shown to be consistent with known expressions for the number-average degree of polymerization and dispersity. It is further demonstrated that these CLDs are well-approximated by negative binomial distributions with appropriate choice of parameters. The negative binomial distribution is thus a useful model for CLDs of reversible deactivation radical polymerizations." @default.
• W2887119438 created "2018-08-22" @default.
• W2887119438 creator A5010776490 @default.
• W2887119438 date "2018-08-08" @default.
• W2887119438 modified "2023-10-07" @default.
• W2887119438 title "The Chain Length Distribution of an Ideal Reversible Deactivation Radical Polymerization" @default.
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• W2887119438 doi "https://doi.org/10.3390/polym10080887" @default.
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