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- W2887128921 abstract "Abstract The present study investigates the effect of a viscous and a non-viscous solvent mixture on the shape of the nanoparticles synthesized in it and applies them for the degradation of an herbicide alachlor. Here, we have used glycerol- water mixed solvent to synthesize zero valent iron nanoparticles under aerobic condition and tested its reductive ability. The microstructural analysis reveals the presence of single flower-like pattern formed from petal-like structures, clustered at the center, while the XRD analysis points out to the presence of single phase particles, having negligible oxide impurities. This refers to the excellent sheathing ability of the viscous solvent during the growth of the nanoparticles. Different experimental conditions and parameters were involved to check the efficiency of the nanoparticles towards alachlor degradation. Within 2 h, almost 90% of alachlor was degraded when the reaction was carried out by ultrasonic agitation under anaerobic condition. The pH variational studies suggested an optimum value of pH 5, at which the highest removal was achieved. Results also emphasized that anaerobic conditions during the reaction lead to higher removal efficacy. Hence, the results predict that nanoscale zero valent synthesized in glycerol medium is a prospective applicant to pesticide remediation." @default.
- W2887128921 created "2018-08-22" @default.
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- W2887128921 date "2018-10-01" @default.
- W2887128921 modified "2023-09-30" @default.
- W2887128921 title "Effect of solvent viscosity on the properties of nanoscale zero valent iron: Insights into alachlor degradation" @default.
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- W2887128921 doi "https://doi.org/10.1016/j.jwpe.2018.07.005" @default.
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