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- W2887132938 abstract "Abstract Step-wise reaction of CdO, Bi2O3, and Cd(NO3)2·4H2O leads to formation of a novel bismuth oxide nitrate, CdBiO2NO3, which completes the family of bismuthite-like MIIBiO2NO3 oxide nitrates. The new compound is tetragonal, I4/mmm, a = 3.9486(1)A, c = 14.2235(2)A; its crystal structure resembles those of PbBiO2NO3 and CaBiO2NO3, except for, probably, different positioning of the nitrate group. The compound is stable until ∼425 °C when it decomposes, in one step, into CdO and a mixture of Bi–Cd oxides. Cd-based analogs of isostructural PbLnO2NO3 (Ln – lanthanides) oxide nitrates are unlikely to exist. We discuss the similarities and differences in the structures of layered oxyhalides and oxynitrates of bismuth and rare-earths." @default.
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- W2887132938 date "2018-10-01" @default.
- W2887132938 modified "2023-09-27" @default.
- W2887132938 title "CdBiO2NO3, a new layered bismuth oxide nitrate" @default.
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- W2887132938 doi "https://doi.org/10.1016/j.solidstatesciences.2018.08.001" @default.
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