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• W2887156710 abstract "This chapter summarizes the self-assembly, structure and properties of molecular gels derived from amide and hydrazide derivatives of (R)-12-hydroxystearic acid (HSA) while comparing them to those of the parent acid. The nature of the aggregates is discussed at different length scales, starting from single molecule structures and progressing to packing within the self-assembled fibrillar networks (SAFINs) of these gels. The structural properties of the gelators are correlated with the bulk properties of their gels. Of note is the observation that many of these gels exhibit thixotropic properties (i.e., they are converted to sols upon application of destructive strain and then return to their gel state when the strain is released). Analyses of the factors within the SAFINs leading to their viscoelastic properties and to the ability of another derivative of HSA to form self-supporting and self-healing gels are presented as well. The results demonstrate how small structural modifications of derivatives of HSA can cause very large changes in the properties of their gels, some of which have important potential consequences to their potential applications." @default.
• W2887156710 created "2018-08-22" @default.
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• W2887156710 date "2018-01-01" @default.
• W2887156710 modified "2023-10-18" @default.
• W2887156710 title "Structure-Property Comparison and Self-Assembly Studies of Molecular Gels Derived from (<i>R</i>)-12-Hydroxystearic Acid Derivatives as Low Molecular Mass Gelators" @default.
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• W2887156710 doi "https://doi.org/10.1021/bk-2018-1296.ch012" @default.
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