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- W2887179898 abstract "Abstract Single crystals of the new compound BaCa(VO)(PO 4 ) 2 have been prepared by solid state reactions below the melting point of the reactants in evacuated quartz tubes. X-ray investigations led to monoclinic symmetry, space group C 2h 5 - P2 1 /c, a = 7.300(1), b = 7.053(1), c = 14.460(1) Å, β = 101,43(1)°, Z = 4. The crystal structure is characterized by layers of corner-and edge-connected PO 4 tetrahedra and VO 1+5 octahedra. There is an unusually short O(1)-O(4) distance in a VO 6 octahedron of 2.44 Å associated with the sharing of edges with PO 4 tetrahedra. The short V-O distance of 1.61 Å indicates a vanadyl group." @default.
- W2887179898 created "2018-08-22" @default.
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- W2887179898 date "1997-05-01" @default.
- W2887179898 modified "2023-09-27" @default.
- W2887179898 title "Kantenverknüpfte VO6-0ktaeder und PO4-Tetraeder in BaCa(VO)(PO4)2 / Edge-Connected VO6 Octahedra and PO4 Tetrahedra in BaCa(VO)(PO4)2" @default.
- W2887179898 doi "https://doi.org/10.1515/znb-1997-0501" @default.
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