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• W2887271779 abstract "Phosphorescence lifetime Zn2+ imaging possesses the advantage over normal fluorescence imaging in offering the more accurate temporal-spatial Zn2+ information. Herein, we report a new phosphorescent cyclometalated Ir(III) complex with a Zn2+-chelator bearing 1,10-phenanthrolin acting as ancillary ligand, Zin-IrDPA, which displays the specific Zn2+-induced enhancement of phosphorescence and phosphorescence lifetime, and the mitochondria-targeting ability. Moreover, its Zn2+-induced phosphorescence lifetime enhancement factor is not affected by medium lipophilicity, viscosity, polarity, and especially ambient oxygen. The reversible tracking of introduced exogenous labile Zn2+ in MCF-7 and HeLa cells via phosphorescence imaging and phosphorescence lifetime imaging (PLIM) have been realized with Zin-IrDPA. Moreover, PLIM with Zin-IrDPA is able to track the SNOC-stimulated endogenous Zn2+ release in mitochondria." @default.
• W2887271779 created "2018-08-22" @default.
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• W2887271779 date "2018-08-13" @default.
• W2887271779 modified "2023-10-12" @default.
• W2887271779 title "Phosphorescence Lifetime Imaging of Labile Zn²⁺ in Mitochondria via a Phosphorescent Iridium(III) Complex" @default.
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• W2887271779 doi "https://doi.org/10.1021/acs.inorgchem.8b01272" @default.
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