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• W2887285697 abstract "The solubility of para-methoxyphenylacetic acid in different solvents is of critical significance for the design and optimization of its purification process via crystallization. The present study illustrates new solid–liquid phase equilibrium data of para-methoxy phenyl acetic acid in water, acetonitrile, propan-2-ol, morpholine, toluene, anisole, and binary (propan-2-ol + water, propan-2-ol + toluene) mixed solvents using a static analytical method from 283.15 to 323.15 K at atmospheric pressure. The highest solubility of para-methoxyphenylacetic acid was observed in propan-2-ol and lowest in water, with the maximum solubility effect for propan-2-ol + toluene binary system obtained at 0.5001 solute-free mole fraction of propan-2-ol. The modified Apelblat equation, λh (Buchowski) equation, and nonrandom two-liquid (NRTL) activity coefficient model were used to correlate the experimental solubility data in pure solvents, whereas the binary solvent systems were modeled using the van’t Hoff–Jouyban–Acree, Apelblat–Jouyban–Acree, and NRTL models, among which the NRTL model exhibited better goodness of fit. Also, for insight into the molecular interactions in the solvent systems, the enthalpy of dissolution has been being evaluated." @default.
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• W2887285697 date "2018-08-06" @default.
• W2887285697 modified "2023-09-27" @default.
• W2887285697 title "Solubility Measurement, Modeling, and Thermodynamic Functions for <i>para</i>-Methoxyphenylacetic Acid in Pure and Mixed Organic and Aqueous Systems" @default.
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• W2887285697 doi "https://doi.org/10.1021/acs.jced.8b00271" @default.
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