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- W2887492028 endingPage "9640" @default.
- W2887492028 startingPage "9631" @default.
- W2887492028 abstract "A dendrimer with rigid branched terminal components was prepared by a copper-catalyzed Hüisgen 1,3-dipolar cycloaddition reaction. A zinc 5,15-diethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrin unit was incorporated at the core of the dendrimer as a receptor site for an added pyridyl ligand. The appearance of an absorption band characteristic of the planar conformer of conjugated chains in the terminal components suggested that the dendrimer adopts a folded higher order structure in dichloromethane at 25 °C. The binding constant between the zinc porphyrin core and a pyridyl ligand was evaluated by means of UV–vis absorption titration and compared with that of a suitable reference compound. The incorporation of the zinc porphyrin core into the folded dendrimer led to considerable suppression of its ligand-binding ability." @default.
- W2887492028 created "2018-08-22" @default.
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- W2887492028 date "2018-08-13" @default.
- W2887492028 modified "2023-10-15" @default.
- W2887492028 title "Ligand-Binding Ability of a Porphyrin Core in a Dendrimer with Rigid Branched Terminal Components" @default.
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- W2887492028 doi "https://doi.org/10.1021/acs.joc.8b00932" @default.
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