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• W2887525344 abstract "The in situ synthesis of the monoanionic chelating dicarbene ligand bis(imidazolin-2-ylidene-1-yl)borate (BISR, R=Me (2a), Et (3a), iPr (4a)) from potassium bis(imidazol-1-yl)dihydridoborate (1) via dialkylation with alkyl iodide and deprotonation with LinBu is described. Treatment of PdI2 and PtCl2 with THF solutions of BISR (1:2) leads to the first neutral homoleptic tetracarbene complexes of these metals 5–9, which are highly soluble in organic media. According to the X-ray structure analyses of 5, 6 and 9, the bischelates adopt centrosymmetric trans double-boat conformations exhibiting the usual stereochemical features. Neutral heteroleptic dicarbene–phosphine complexes of palladium and platinum of the general formula [M(BISR)(I)(PEt3)] (14–19) result in good yields from the reaction of BISR with [M(μ-Cl)Cl(PEt3)]2 (2:1). From X-ray structure determinations of 15, 16 and 18 two findings should be emphasized: the heavy out-of-plane bending of the boat-shaped chelate ring (which is the cause of chirality of these complexes), and the existence of two rather different M to carbene carbon bond lengths (indicating the stronger trans influence of PEt3 as compared to I−). With Au(Cl)(PPh3), instead of forming small chelate rings, the bidentate ligands BISR switch to a μ2-η1:η1-bridging ligand type of function giving rise to the compounds 10–12. An X-ray study of 11 reveals the structure of a 12-membered dimetallacycle in a twisted boat-like conformation with a trans-annular Au⋯Au separation of 3.3610(7) Å, i.e. only a weak interaction. In addition, two by-products — the three-coordinate iodobis(triphenylphosphine)gold(I) (13) and trans-diiodobis(triethylphosphine)palladium(II) (20) — have been structurally characterized." @default.
• W2887525344 created "2018-08-22" @default.
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• W2887525344 date "2001-01-01" @default.
• W2887525344 modified "2023-10-17" @default.
• W2887525344 title "Homoleptic carbene complexes" @default.
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• W2887525344 doi "https://doi.org/10.1016/s0020-1693(00)00323-6" @default.
• W2887525344 hasPublicationYear "2001" @default.
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