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- W2887537266 abstract "Beyond the lanthanide organometallic single-ion magnet (SIM) (Cp*)Er(COT)1 ([Cp*]- = pentamethylcyclopentadienide; COT2- = cyclooctatetraenide) that has a good performance, we managed to replace one coordinated carbon atom on the [Cp*]- ring by a soft phosphorus atom and obtained (Dsp)Er(COT) (CCDC No. ; 1835955; Dsp- = 3,4-dimethyl-2,5-bis(trimethylsilyl)phospholyl) whose sandwich structure is reported here for the first time. This substitution results in a remarkable change of magnetic dynamics. It exhibits slow magnetic relaxation under a zero applied direct current (DC) magnetic field with an energy barrier (Δ/kB) of 358 K and magnetic hysteresis up to 9 K, both of which are higher than those of (Cp*)Er(COT). With the descended local symmetry of (Dsp)Er(COT), the energy barrier and blocking temperature (TB) both improve unexpectedly and are among the highest ones in Er(iii)-based single-molecule magnets (SMMs)." @default.
- W2887537266 created "2018-08-22" @default.
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- W2887537266 date "2018-01-01" @default.
- W2887537266 modified "2023-10-16" @default.
- W2887537266 title "A soft phosphorus atom to “harden” an erbium(<scp>iii</scp>) single-ion magnet" @default.
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- W2887537266 doi "https://doi.org/10.1039/c8sc01626g" @default.
- W2887537266 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6180309" @default.
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